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Simultaneous extraction and preconcentration of copper, silver and palladium with modified alumina and their determination by electrothermal atomic absorption spectrometry

Mohammad Ali Taher ,  Zahra Daliri ,  Hamid Fazelirad

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Citation:  Mohammad Ali Taher, Zahra Daliri, Hamid Fazelirad. Simultaneous extraction and preconcentration of copper, silver and palladium with modified alumina and their determination by electrothermal atomic absorption spectrometry[J]. Chinese Chemical Letters, 2014, 25(4): 649-654. doi: 10.1016/j.cclet.2013.12.025 shu

Simultaneous extraction and preconcentration of copper, silver and palladium with modified alumina and their determination by electrothermal atomic absorption spectrometry

    • 通讯作者: Hamid Fazelirad,
摘要: In the present work, an easy solid phase extraction method using alumina modified with polyethylenimine as a new adsorbent was applied to the simultaneous extraction of copper, silver, and palladium ions prior to their determination with electrothermal atomic absorption spectrometry. The analytical procedure involved the complex formation of these cations with polyethylenimine as a chelating agent in buffer media of pH 7.0. Under the optimum conditions, a preconcentration factor of 200, 150, and 200, precision of ±5.4%, ±4.7%, and ±5.2% and linear calibration ranges of 15.0-140, 4.0-93, and 7.5-125 ng/L (in original solution) for Cu, Ag, and Pd were obtained, respectively. Also detection limits of 3.9, 1.1, and 2.0 ng/L were obtained for Cu, Ag, and Pd, respectively. The proposed method was applied to the determination of copper, silver, and palladium in some real samples with satisfactory results.

English

    1. [1] G. Huand, R.L. Deming, Speciation of bio-available chromium in soils by solidphase extraction and graphite furnace atomic absorption spectrometry, Anal. Chim. Acta 535 (2005) 237-242.[1] G. Huand, R.L. Deming, Speciation of bio-available chromium in soils by solidphase extraction and graphite furnace atomic absorption spectrometry, Anal. Chim. Acta 535 (2005) 237-242.

    2. [2] O. Mikkelsen, S.M. Skogvold, K.H. Schrøder, Continouos heavy metal monitoring system for application in river and seawater, Electroanalysis 17 (2005) 431-439.[2] O. Mikkelsen, S.M. Skogvold, K.H. Schrøder, Continouos heavy metal monitoring system for application in river and seawater, Electroanalysis 17 (2005) 431-439.

    3. [3] H. Ashkenani, M.A. Taher, Selective voltammetric determination of Cu(II) based on multiwalled carbon nanotube and nano-porous Cu-ion imprinted polymer, J. Electroanal. Chem. 683 (2012) 80-87.[3] H. Ashkenani, M.A. Taher, Selective voltammetric determination of Cu(II) based on multiwalled carbon nanotube and nano-porous Cu-ion imprinted polymer, J. Electroanal. Chem. 683 (2012) 80-87.

    4. [4] S. Jahandari, M.A. Taher, H. Fazelirad, I. Sheikhshoai, Anodic stripping voltammetry of silver(I) using a carbon paste electrode modified with multi-walled carbon nanotubes, Microchim. Acta 180 (2013) 347-354.[4] S. Jahandari, M.A. Taher, H. Fazelirad, I. Sheikhshoai, Anodic stripping voltammetry of silver(I) using a carbon paste electrode modified with multi-walled carbon nanotubes, Microchim. Acta 180 (2013) 347-354.

    5. [5] P. Liang, E. Zhao, F. Li, Dispersive liquid-liquid microextraction preconcentration of palladium in water samples and determination by graphite furnace atomic absorption spectrometry, Talanta 77 (2009) 1854-1857.[5] P. Liang, E. Zhao, F. Li, Dispersive liquid-liquid microextraction preconcentration of palladium in water samples and determination by graphite furnace atomic absorption spectrometry, Talanta 77 (2009) 1854-1857.

    6. [6] H. Fazelirad, M.A. Taher, Ligandless, ion pair-based and ultrasound assisted emulsification solidified floating organic drop microextraction for simultaneous preconcentration of ultra-trace amounts of gold and thallium and determination by GFAAS, Talanta 103 (2013) 375-383.[6] H. Fazelirad, M.A. Taher, Ligandless, ion pair-based and ultrasound assisted emulsification solidified floating organic drop microextraction for simultaneous preconcentration of ultra-trace amounts of gold and thallium and determination by GFAAS, Talanta 103 (2013) 375-383.

    7. [7] M.A. Cheraghi, H. Taher, Fazelirad, Voltammetric sensing of thallium at a carbon paste electrode modified with a crown ether, Microchim. Acta 180 (2013) 1157-1163.[7] M.A. Cheraghi, H. Taher, Fazelirad, Voltammetric sensing of thallium at a carbon paste electrode modified with a crown ether, Microchim. Acta 180 (2013) 1157-1163.

    8. [8] A.A. Atia, A.M. Donia, A.M. Yousif, Synthesis of amine and thio chelating resins and study of their interaction with zinc(II), cadmium(II) and mercury(II), React, Funct. Polym. 56 (2003) 75-82.[8] A.A. Atia, A.M. Donia, A.M. Yousif, Synthesis of amine and thio chelating resins and study of their interaction with zinc(II), cadmium(II) and mercury(II), React, Funct. Polym. 56 (2003) 75-82.

    9. [9] M. Zeeb, M.R. Ganjali, P. Norouzi, M.R. Kalaee, Separation and preconcentration system based on microextraction with ionic liquid for determination of copper in water and food samples by stopped-flow injection spectrofluorimetry, Food Chem. Toxicol. 49 (2011) 1086-1091.[9] M. Zeeb, M.R. Ganjali, P. Norouzi, M.R. Kalaee, Separation and preconcentration system based on microextraction with ionic liquid for determination of copper in water and food samples by stopped-flow injection spectrofluorimetry, Food Chem. Toxicol. 49 (2011) 1086-1091.

    10. [10] S. Abbasi, H. Khani, R. Tabaraki, Determination of ultra trace levels of copper in food samples by a highly sensitive adsorptive stripping voltammetric method, Food Chem. 123 (2010) 507-512.[10] S. Abbasi, H. Khani, R. Tabaraki, Determination of ultra trace levels of copper in food samples by a highly sensitive adsorptive stripping voltammetric method, Food Chem. 123 (2010) 507-512.

    11. [11] E.A. Takara, S.D. Pasini-Cabello, S. Cerutti, J.A. Gasquez, L.D. Martinez, On-line preconcentration/determination of copper in parenteral solutions using activated carbon by inductively coupled plasma optical emission spectrometry, J. Pharm. Biomed. Anal. 39 (2005) 735-739.[11] E.A. Takara, S.D. Pasini-Cabello, S. Cerutti, J.A. Gasquez, L.D. Martinez, On-line preconcentration/determination of copper in parenteral solutions using activated carbon by inductively coupled plasma optical emission spectrometry, J. Pharm. Biomed. Anal. 39 (2005) 735-739.

    12. [12] M. Faraji, Y. Yamini, S. Shariati, Application of cotton as a solid phase extraction sorbent for on-line preconcentration of copper in water samples prior to inductively coupled plasma optical emission spectrometry determination, J. Hazard. Mater. 166 (2009) 1383-1388.[12] M. Faraji, Y. Yamini, S. Shariati, Application of cotton as a solid phase extraction sorbent for on-line preconcentration of copper in water samples prior to inductively coupled plasma optical emission spectrometry determination, J. Hazard. Mater. 166 (2009) 1383-1388.

    13. [13] M.H. Mashhadizadeh, M. Pesteh, M. Talakesh, et al., Solid phase extraction of copper (II) by sorption on octadecyl silica membrane disk modified with a new Schiff base and determination with atomic absorption spectrometry, Spectrochim. Acta B 63 (2008) 885-888.[13] M.H. Mashhadizadeh, M. Pesteh, M. Talakesh, et al., Solid phase extraction of copper (II) by sorption on octadecyl silica membrane disk modified with a new Schiff base and determination with atomic absorption spectrometry, Spectrochim. Acta B 63 (2008) 885-888.

    14. [14] B. Buke, U. Divrikli, M. Soylak, L. Elci, On-line preconcentration of copper as its pyrocatechol violet complex on Chromosorb 105 for flame atomic absorption spectrometric determinations, J. Hazard. Mater. 163 (2009) 1298-1302.[14] B. Buke, U. Divrikli, M. Soylak, L. Elci, On-line preconcentration of copper as its pyrocatechol violet complex on Chromosorb 105 for flame atomic absorption spectrometric determinations, J. Hazard. Mater. 163 (2009) 1298-1302.

    15. [15] M.C. Yebra, N. Carro, A. Moreno-Cid, Optimization of a field flow pre-concentration system by experimental design for the determination of copper in sea water by flow-injection-atomic absorption spectrometry, Spectrochim. Acta B 57 (2002) 85-93.[15] M.C. Yebra, N. Carro, A. Moreno-Cid, Optimization of a field flow pre-concentration system by experimental design for the determination of copper in sea water by flow-injection-atomic absorption spectrometry, Spectrochim. Acta B 57 (2002) 85-93.

    16. [16] A.N. Anthemidis, K.G. Ioannou, On-line sequential injection dispersive liquidliquid microextraction system for flame atomic absorption spectrometric determination of copper and lead in water samples, Talanta 79 (2009) 86-91.[16] A.N. Anthemidis, K.G. Ioannou, On-line sequential injection dispersive liquidliquid microextraction system for flame atomic absorption spectrometric determination of copper and lead in water samples, Talanta 79 (2009) 86-91.

    17. [17] K. Alizadeh, S. Zohrevand, A.R. Ghiasvand, et al., Selective homogeneous liquid- liquid extraction and preconcentration of copper(II) into a micro droplet using a benzo-substituted macrocyclic diamide, and its determination by electrothermal atomic absorption spectrometry, Microchim. Acta 168 (2010) 115-121.[17] K. Alizadeh, S. Zohrevand, A.R. Ghiasvand, et al., Selective homogeneous liquid- liquid extraction and preconcentration of copper(II) into a micro droplet using a benzo-substituted macrocyclic diamide, and its determination by electrothermal atomic absorption spectrometry, Microchim. Acta 168 (2010) 115-121.

    18. [18] X. Wen, L. Kong, M. Chen, et al., A new coupling of spectrophotometric determination with ultrasound-assisted emulsification dispersive liquid-liquid microextraction of trace silver, Spectrochim. Acta A 97 (2012) 782-787.[18] X. Wen, L. Kong, M. Chen, et al., A new coupling of spectrophotometric determination with ultrasound-assisted emulsification dispersive liquid-liquid microextraction of trace silver, Spectrochim. Acta A 97 (2012) 782-787.

    19. [19] M. Hosoba, K. Oshita, R.K. Katarina, et al., Synthesis of novel chitosan resin possessing histidine moiety and its application to the determination of trace silver by ICP-AES coupled with triplet automated-pretreatment system, Anal. Chim. Acta 639 (2009) 51-56.[19] M. Hosoba, K. Oshita, R.K. Katarina, et al., Synthesis of novel chitosan resin possessing histidine moiety and its application to the determination of trace silver by ICP-AES coupled with triplet automated-pretreatment system, Anal. Chim. Acta 639 (2009) 51-56.

    20. [20] R.K. Katarina, T. Takayanagi, M. Oshima, S. Motomizu, Synthesis of a chitosanbased chelating resin and its application to the selective concentration and ultratrace determination of silver in environmental water samples, Anal. Chim. Acta 558 (2006) 246-253.[20] R.K. Katarina, T. Takayanagi, M. Oshima, S. Motomizu, Synthesis of a chitosanbased chelating resin and its application to the selective concentration and ultratrace determination of silver in environmental water samples, Anal. Chim. Acta 558 (2006) 246-253.

    21. [21] C.K. Christou, A.N. Anthemidis, Flow injection on-line displacement/solid phase extraction system coupled with flame atomic absorption spectrometry for selective trace silver determination in water samples, Talanta 78 (2009) 144-149.[21] C.K. Christou, A.N. Anthemidis, Flow injection on-line displacement/solid phase extraction system coupled with flame atomic absorption spectrometry for selective trace silver determination in water samples, Talanta 78 (2009) 144-149.

    22. [22] C.S.T. Arau′ jo, V.N. Alves, H.C. Rezende, N.M.M. Coelho, Development of a flow system for the determination of low concentrations of silver using Moringa oleifera seeds as biosorbent and flame atomic absorption spectrometry, Microchem. J. 96 (2010) 82-85.[22] C.S.T. Arau′ jo, V.N. Alves, H.C. Rezende, N.M.M. Coelho, Development of a flow system for the determination of low concentrations of silver using Moringa oleifera seeds as biosorbent and flame atomic absorption spectrometry, Microchem. J. 96 (2010) 82-85.

    23. [23] J.L. Manzoori, G.K. Nezhad, Selective cloud point extraction and preconcentration of trace amounts of silver as a dithizone complex prior to flame atomic absorption spectrometric determination, Anal. Chim. Acta 484 (2003) 155-161.[23] J.L. Manzoori, G.K. Nezhad, Selective cloud point extraction and preconcentration of trace amounts of silver as a dithizone complex prior to flame atomic absorption spectrometric determination, Anal. Chim. Acta 484 (2003) 155-161.

    24. [24] J. Medved, P. Matus, M. Bujdos, J. Kubova, Gold and silver determination in waters by SPHERON Thiol 1000 preconcentration and ETAAS, Chem. Pap. 60 (2006) 27-31.[24] J. Medved, P. Matus, M. Bujdos, J. Kubova, Gold and silver determination in waters by SPHERON Thiol 1000 preconcentration and ETAAS, Chem. Pap. 60 (2006) 27-31.

    25. [25] M.A. Rahmana, S. Kaneco, M.N. Amina, T. Suzuki, K. Ohta, Determination of silver in environmental samples by tungsten wire preconcentration method - electrothermal atomic absorption spectrometry, Talanta 62 (2004) 1047-1050.[25] M.A. Rahmana, S. Kaneco, M.N. Amina, T. Suzuki, K. Ohta, Determination of silver in environmental samples by tungsten wire preconcentration method - electrothermal atomic absorption spectrometry, Talanta 62 (2004) 1047-1050.

    26. [26] H. Ashkenani, M.A. Taher, Use of ionic liquid in simultaneous microextraction procedure for determination of gold and silver by ETAAS, Microchem. J. 103 (2012) 185-190.[26] H. Ashkenani, M.A. Taher, Use of ionic liquid in simultaneous microextraction procedure for determination of gold and silver by ETAAS, Microchem. J. 103 (2012) 185-190.

    27. [27] M. Moldovan, M.M. Gómez, M.A. Palacios, On-line preconcentration of palladium on alumina microcolumns and determination in urban waters by inductively coupled plasma mass spectrometry, Anal. Chim. Acta 478 (2003) 209-217.[27] M. Moldovan, M.M. Gómez, M.A. Palacios, On-line preconcentration of palladium on alumina microcolumns and determination in urban waters by inductively coupled plasma mass spectrometry, Anal. Chim. Acta 478 (2003) 209-217.

    28. [28] J. Fang, L.W. Liu, X.P. Yan, Minimization of mass interferences in quadrupole inductively coupled plasma mass spectrometric (ICP-MS) determination of palladium using a flow injection on-line displacement solid-phase extraction protocol, Spectrochim. Acta B 61 (2006) 864-869.[28] J. Fang, L.W. Liu, X.P. Yan, Minimization of mass interferences in quadrupole inductively coupled plasma mass spectrometric (ICP-MS) determination of palladium using a flow injection on-line displacement solid-phase extraction protocol, Spectrochim. Acta B 61 (2006) 864-869.

    29. [29] M.V.B. Krishna, M. Ranjit, K. Chandrasekaran, G. Venkateswarlu, D. Karunasagar, On-line preconcentration and recovery of palladium from waters using polyaniline (PANI) loaded in mini-column and determination by ICP-MS; elimination of spectral interferences, Talanta 79 (2009) 1454-1463.[29] M.V.B. Krishna, M. Ranjit, K. Chandrasekaran, G. Venkateswarlu, D. Karunasagar, On-line preconcentration and recovery of palladium from waters using polyaniline (PANI) loaded in mini-column and determination by ICP-MS; elimination of spectral interferences, Talanta 79 (2009) 1454-1463.

    30. [30] M.R. Jamali, Y. Assadi, F. Shemirani, M. Salavati-Niasari, Application of thiophene- 2-carbaldehyde-modified mesoporous silica as a new sorbent for separation and preconcentration of palladium prior to inductively coupled plasma atomic emission spectrometric determination, Talanta 71 (2007) 1524-1529.[30] M.R. Jamali, Y. Assadi, F. Shemirani, M. Salavati-Niasari, Application of thiophene- 2-carbaldehyde-modified mesoporous silica as a new sorbent for separation and preconcentration of palladium prior to inductively coupled plasma atomic emission spectrometric determination, Talanta 71 (2007) 1524-1529.

    31. [31] J. Nakajima, M. Ohno, K. Chikama, T. Seki, K. Oguma, Determination of traces of palladium in stream sediment and auto catalyst by FI-ICP-OES using on-line separation and preconcentration with QuadraSil TA, Talanta 79 (2009) 1050- 1054.[31] J. Nakajima, M. Ohno, K. Chikama, T. Seki, K. Oguma, Determination of traces of palladium in stream sediment and auto catalyst by FI-ICP-OES using on-line separation and preconcentration with QuadraSil TA, Talanta 79 (2009) 1050- 1054.

    32. [32] M. Muzikar, C. Fontàs, M. Hidalgo, J. Havel, V. Salvadó, A preconcentration system using polyamine Metalfix-Chelamine resin for the on-line determination of palladium(II) and platinum(IV) by inductively coupled plasma optical emission spectrometry, Talanta 70 (2006) 1081-1086.[32] M. Muzikar, C. Fontàs, M. Hidalgo, J. Havel, V. Salvadó, A preconcentration system using polyamine Metalfix-Chelamine resin for the on-line determination of palladium(II) and platinum(IV) by inductively coupled plasma optical emission spectrometry, Talanta 70 (2006) 1081-1086.

    33. [33] H. Ebrahimzadeh, N. Tavassoli, M.M. Amini, Y. Fazaeli, H. Abedi, Determination of very low levels of gold and palladium in wastewater and soil samples by atomic absorption after preconcentration on modified MCM-48 and MCM-41 silica, Talanta 81 (2010) 1183-1188.[33] H. Ebrahimzadeh, N. Tavassoli, M.M. Amini, Y. Fazaeli, H. Abedi, Determination of very low levels of gold and palladium in wastewater and soil samples by atomic absorption after preconcentration on modified MCM-48 and MCM-41 silica, Talanta 81 (2010) 1183-1188.

    34. [34] B. Godlewska-Zylkiewiczand, M. Zaleska, Preconcentration of palladium in a flow-through electrochemical cell for determination by graphite furnace atomic absorption spectrometry, Anal. Chim. Acta 462 (2002) 305-312.[34] B. Godlewska-Zylkiewiczand, M. Zaleska, Preconcentration of palladium in a flow-through electrochemical cell for determination by graphite furnace atomic absorption spectrometry, Anal. Chim. Acta 462 (2002) 305-312.

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  • 发布日期:  2014-01-31
  • 收稿日期:  2013-11-27
  • 网络出版日期:  2013-12-31
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