可重复使用CuO纳米粒子催化微波辅助的腈和NaN<sub>3</sub>环加成反应合成5-取代1<i>H</i>-四唑类

引用本文: R. D. Padmaja, Sourav Rej, Kaushik Chanda. 可重复使用CuO纳米粒子催化微波辅助的腈和NaN₃环加成反应合成5-取代1H-四唑类[J]. 催化学报, 2017, 38(11): 1918-1924. doi: 10.1016/S1872-2067(17)62920-6 shu

Citation: R. D. Padmaja, Sourav Rej, Kaushik Chanda. Environmentally friendly, microwave-assisted synthesis of 5-substituted 1H-tetrazoles by recyclable CuO nanoparticles via (3+2) cycloaddition of nitriles and NaN₃[J]. Chinese Journal of Catalysis, 2017, 38(11): 1918-1924. doi: 10.1016/S1872-2067(17)62920-6 shu

可重复使用CuO纳米粒子催化微波辅助的腈和NaN₃环加成反应合成5-取代1H-四唑类

a 韦洛尔大学高等科学学院化学系, 韦洛尔 632014, 印度;
b 生物工程与纳米技术研究所, 138669, 新加坡

摘要: 将可重复使用的CuO纳米粒子成功用于催化微波辅助的腈和NaN₃[3+2]环加成反应高效合成5-取代1H-四唑类化合物.该法突出特点为成本低、合成快、稳定性高、可重复使用、反应条件温和、无需任何添加物、官能团兼容性好和产率高.这种环境友好的微波辅助纳米粒子催化合成策略可望替代现有的涉及常规路易斯酸催化剂方法，以及作为一种简易的合成特殊化合物的方法.

关键词:

English

Environmentally friendly, microwave-assisted synthesis of 5-substituted 1H-tetrazoles by recyclable CuO nanoparticles via (3+2) cycloaddition of nitriles and NaN₃

a Department of Chemistry, School of Advanced Sciences, VIT University, Vellore-632014, India;
b Institute of Bioengineering and Nanotechnology, A^*STAR. 31 Biopolis Way, Singapore-138669
Received Date: 07 August 2017
Revised Date: 16 September 2017

Abstract: Recyclable CuO nanoparticles were successfully employed to catalyze the microwave-assisted (3+2) cycloaddition reaction between nitriles and NaN₃ to efficiently synthesize 5-substituted 1H-tetrazoles. The salient features associated with this protocol are its cost effectiveness, rapid synthesis, stability, reusability, mild reaction conditions without any additives, high tolerance to various func-tional groups, and excellent yields under microwave irradiation. This environmentally friendly, microwave-assisted, nanoparticle-catalyzed synthetic methodology is seen as an alternative to conventional procedures that involve Lewis acid catalysts and a simple operation to the privileged scaffold.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

可重复使用CuO纳米粒子催化微波辅助的腈和NaN₃环加成反应合成5-取代1H-四唑类

English

Environmentally friendly, microwave-assisted synthesis of 5-substituted 1H-tetrazoles by recyclable CuO nanoparticles via (3+2) cycloaddition of nitriles and NaN₃

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

可重复使用CuO纳米粒子催化微波辅助的腈和NaN3环加成反应合成5-取代1H-四唑类

English

Environmentally friendly, microwave-assisted synthesis of 5-substituted 1H-tetrazoles by recyclable CuO nanoparticles via (3+2) cycloaddition of nitriles and NaN3

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

可重复使用CuO纳米粒子催化微波辅助的腈和NaN₃环加成反应合成5-取代1H-四唑类

Environmentally friendly, microwave-assisted synthesis of 5-substituted 1H-tetrazoles by recyclable CuO nanoparticles via (3+2) cycloaddition of nitriles and NaN₃

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