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Ce-Beta分子筛的制备及其催化性能

唐波 ,  戴卫理 ,  孙晓明 ,  武光军 ,  李兰冬 ,  关乃佳 ,  Michael Hunger

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引用本文: 唐波, 戴卫理, 孙晓明, 武光军, 李兰冬, 关乃佳, Michael Hunger. Ce-Beta分子筛的制备及其催化性能[J]. 催化学报, 2015, 36(6): 801-805. doi: 10.1016/S1872-2067(14)60277-1 shu
Citation:  Bo Tang, Weili Dai, Xiaoming Sun, Guangjun Wu, Landong Li, Naijia Guan, Michael Hunger. Incorporation of cerium atoms into Al-free Beta zeolite framework for catalytic application[J]. Chinese Journal of Catalysis, 2015, 36(6): 801-805. doi: 10.1016/S1872-2067(14)60277-1 shu

Ce-Beta分子筛的制备及其催化性能

    通讯作者: 戴卫理,电话/传真: (022)23500341; 电子信箱: weilidai@nankai.edu.cn
  • 基金项目:

    国家自然科学基金(21373119) (21373119)

    教育部创新团队(IRT13022, IRT13R30) (IRT13022, IRT13R30)

    111计划(B12015) (B12015)

    德国科学基金会. 

摘要: 采用简单、易重现的两步后合成法成功制备了Ce-Beta分子筛. 制备过程中, H-Beta分子筛首先经过脱铝处理得到Si-Beta分子筛, 然后再以异丙醇铈为前驱体, 通过干法浸渍的途径向Si-Beta分子筛引入Ce (IV). 利用XRD, FT-IR, UV-Vis和1H MAS NMR等对其结构进行了表征, 结果表明, Ce(IV)物种以四配位的形式成功引入Beta分子筛的骨架, Ce原子进入分子筛骨架的机理通过DRIFT光谱得以证实. 通过环氧化合物水合制备1,2-二醇反应对所制的Ce-Beta催化剂进行了催化性能评价.

English

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  • 发布日期:  2015-06-20
  • 收稿日期:  2014-11-04
  • 网络出版日期:  2014-12-04
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