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单一微孔模板剂一锅法制备多级结构ZSM-5沸石

葛同广 ,  华子乐 ,  贺晓耘 ,  朱颜 ,  任文超 ,  陈立松 ,  张玲霞 ,  陈航榕 ,  林初城 ,  姚鹤良 ,  施剑林

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引用本文: 葛同广, 华子乐, 贺晓耘, 朱颜, 任文超, 陈立松, 张玲霞, 陈航榕, 林初城, 姚鹤良, 施剑林. 单一微孔模板剂一锅法制备多级结构ZSM-5沸石[J]. 催化学报, 2015, 36(6): 866-873. doi: 10.1016/S1872-2067(14)60263-1 shu
Citation:  Tongguang Ge, Zile Hua, Xiaoyun He, Yan Zhu, Wenchao Ren, Lisong Chen, Lingxia Zhang, Hangrong Chen, Chucheng Lin, Heliang Yao, Jianlin Shi. One-pot synthesis of hierarchically structured ZSM-5 zeolites using single micropore-template[J]. Chinese Journal of Catalysis, 2015, 36(6): 866-873. doi: 10.1016/S1872-2067(14)60263-1 shu

单一微孔模板剂一锅法制备多级结构ZSM-5沸石

    通讯作者: 华子乐,电话: (021)52412708; 传真: (021)52413122; 电子信箱: huazl@mail.sic.ac.cn;施剑林,电话: (021)52412712; 传真: (021)52413122; 电子信箱: jlshi@mail.sic.ac.cn; 华子乐,电话: (021)52412708; 传真: (021)52413122; 电子信箱: huazl@mail.sic.ac.cn;施剑林,电话: (021)52412712; 传真: (021)52413122; 电子信箱: jlshi@mail.sic.ac.cn
  • 基金项目:

    国家重点基础研究发展计划(973计划, 2013CB933200) (973计划, 2013CB933200)

    国家高技术研究发展计划(863计划, 2012AA062703) (863计划, 2012AA062703)

    国家杰出青年科学基金(51225202) (51225202)

    重质油国家重点实验室开放课题(SKLOP201402003). (SKLOP201402003)

摘要: 以微孔模板剂四丙基氢氧化铵为单一模板剂, 采用一种温和的低温水热一锅法工艺, 成功制备出多级结构ZSM-5沸石(HSZs). 与传统的双模板法和后处理法相比, 这种结合了沸石生长与后刻蚀于一体的新方法, 不仅减少了模板剂的用量及二次酸/碱刻蚀、煅烧造成的环境污染, 同时也极大地简化了合成工艺. 利用XRD, N2吸附, SEM, TEM, XRF, 27Al NMR与NH3-TPD等测试手段对合成的HSZs进行了全面表征, 并提出了一种"成核/生长-刻蚀/再晶化"的形成机理. 与传统ZSM-5沸石相比, 这种具有均一梭型形貌的HSZs具有高的水热稳定性, 并在三异丙苯催化裂解的探针反应中表现出优异催化性能和较长使用寿命.

English

    1. [1] Corma A. J Catal, 2003, 216: 298[1] Corma A. J Catal, 2003, 216: 298

    2. [2] Primo A, Garcia H. Chem Soc Rev, 2014, 43: 7548[2] Primo A, Garcia H. Chem Soc Rev, 2014, 43: 7548

    3. [3] Urata K, Furukawa S, Komatsu T. Appl Catal A, 2014, 475: 335[3] Urata K, Furukawa S, Komatsu T. Appl Catal A, 2014, 475: 335

    4. [4] Schmidt F, Hoffmann C, Giordanino F, Bordiga S, Simon P, Carrillo-Cabrera W, Kaskel S. J Catal, 2013, 307: 238[4] Schmidt F, Hoffmann C, Giordanino F, Bordiga S, Simon P, Carrillo-Cabrera W, Kaskel S. J Catal, 2013, 307: 238

    5. [5] Mei C S, Wen P Y, Liu Z C, Liu H X, Wang Y D, Yang W M, Xie Z K, Hua W M, Gao Z. J Catal, 2008, 258: 243[5] Mei C S, Wen P Y, Liu Z C, Liu H X, Wang Y D, Yang W M, Xie Z K, Hua W M, Gao Z. J Catal, 2008, 258: 243

    6. [6] Kim J, Choi M, Ryoo R. J Catal, 2010, 269: 219[6] Kim J, Choi M, Ryoo R. J Catal, 2010, 269: 219

    7. [7] Hu Y Y, Liu C, Zhang Y H, Ren N, Tang Y. Microporous Mesoporous Mater, 2009, 119: 306[7] Hu Y Y, Liu C, Zhang Y H, Ren N, Tang Y. Microporous Mesoporous Mater, 2009, 119: 306

    8. [8] Kim J C, Cho K, Ryoo R. Appl Catal A, 2014, 470: 420[8] Kim J C, Cho K, Ryoo R. Appl Catal A, 2014, 470: 420

    9. [9] Choi M, Cho H S, Srivastava R, Venkatesan C, Choi D H, Ryoo R. Nat Mater, 2006, 5: 718[9] Choi M, Cho H S, Srivastava R, Venkatesan C, Choi D H, Ryoo R. Nat Mater, 2006, 5: 718

    10. [10] Perez-Ramirez J, Christensen C H, Egeblad K, Christensen C H, Groen J C. Chem Soc Rev, 2008, 37: 2530[10] Perez-Ramirez J, Christensen C H, Egeblad K, Christensen C H, Groen J C. Chem Soc Rev, 2008, 37: 2530

    11. [11] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246[11] Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R. Nature, 2009, 461: 246

    12. [12] Moliner M, Rey F, Corma A. Angew Chem Int Ed, 2013, 52: 13880[12] Moliner M, Rey F, Corma A. Angew Chem Int Ed, 2013, 52: 13880

    13. [13] Möller K, Bein T. Chem Soc Rev, 2013, 42: 3689[13] Möller K, Bein T. Chem Soc Rev, 2013, 42: 3689

    14. [14] Meng X J, Xiao F S. Chem Rev, 2014, 114: 1521[14] Meng X J, Xiao F S. Chem Rev, 2014, 114: 1521

    15. [15] Ji Y J, Xu H, Wang D R, Xu L, Ji P, Wu H H, Wu P. ACS Catal, 2013, 3: 1892[15] Ji Y J, Xu H, Wang D R, Xu L, Ji P, Wu H H, Wu P. ACS Catal, 2013, 3: 1892

    16. [16] Jin H L, Ansari M B, Jeong E Y, Park S E. J Catal, 2012, 291: 55[16] Jin H L, Ansari M B, Jeong E Y, Park S E. J Catal, 2012, 291: 55

    17. [17] Hamdy M S, Mul G. ChemCatChem, 2013, 5: 3156[17] Hamdy M S, Mul G. ChemCatChem, 2013, 5: 3156

    18. [18] Tang B, Dai W L, Sun X M, Guan N J, Li L D, Hunger M. Green Chem, 2014, 16: 2281[18] Tang B, Dai W L, Sun X M, Guan N J, Li L D, Hunger M. Green Chem, 2014, 16: 2281

    19. [19] White R J, Fischer A, Goebel C, Thomas A. J Am Chem Soc, 2014, 136: 2715[19] White R J, Fischer A, Goebel C, Thomas A. J Am Chem Soc, 2014, 136: 2715

    20. [20] Emdadi L, Wu Y Q, Zhu G H, Chang C C, Fan W, Pham T, Lobo R F, Liu D X. Chem Mater, 2014, 26: 1345[20] Emdadi L, Wu Y Q, Zhu G H, Chang C C, Fan W, Pham T, Lobo R F, Liu D X. Chem Mater, 2014, 26: 1345

    21. [21] Emdadi L, Liu D X. J Mater Chem A, 2014, 2: 13388[21] Emdadi L, Liu D X. J Mater Chem A, 2014, 2: 13388

    22. [22] Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger R J, Chmelka B F, Ryoo R. Science, 2011, 333: 328[22] Na K, Jo C, Kim J, Cho K, Jung J, Seo Y, Messinger R J, Chmelka B F, Ryoo R. Science, 2011, 333: 328

    23. [23] Zhou J, Hua Z L, Shi J L, He Q J, Guo L M, Ruan M L. Chem Eur J, 2009, 15: 12949[23] Zhou J, Hua Z L, Shi J L, He Q J, Guo L M, Ruan M L. Chem Eur J, 2009, 15: 12949

    24. [24] Zhou J, Hua Z L, Liu Z C, Wu W, Zhu Y, Shi J L. ACS Catal, 2011, 1: 287[24] Zhou J, Hua Z L, Liu Z C, Wu W, Zhu Y, Shi J L. ACS Catal, 2011, 1: 287

    25. [25] Zhu Y, Hua Z L, Zhou J, Wang L J, Zhao J J, Gong Y, Wu W, Ruan M L, Shi J L. Chem Eur J, 2011, 17: 14618[25] Zhu Y, Hua Z L, Zhou J, Wang L J, Zhao J J, Gong Y, Wu W, Ruan M L, Shi J L. Chem Eur J, 2011, 17: 14618

    26. [26] Liu J Y, Wang J G, Li N, Zhao H, Zhou H J, Sun P C, Chen T H. Langmuir, 2012, 28: 8600[26] Liu J Y, Wang J G, Li N, Zhao H, Zhou H J, Sun P C, Chen T H. Langmuir, 2012, 28: 8600

    27. [27] Pérez-Ramírez J, Abelló S, Bonilla A, Groen J C. Adv Funct Mater, 2009, 19: 164[27] Pérez-Ramírez J, Abelló S, Bonilla A, Groen J C. Adv Funct Mater, 2009, 19: 164

    28. [28] Pérez-Ramírez J, Verboekend D, Bonilla A, Abello S. Adv Funct Mater, 2009, 19: 3972[28] Pérez-Ramírez J, Verboekend D, Bonilla A, Abello S. Adv Funct Mater, 2009, 19: 3972

    29. [29] Milina M, Mitchell S, Michels N L, Kenvin J, Pérez-Ramírez J. J Catal, 2013, 308: 398[29] Milina M, Mitchell S, Michels N L, Kenvin J, Pérez-Ramírez J. J Catal, 2013, 308: 398

    30. [30] Abelló S, Bonilla A, Pérez-Ramírez J. Appl Catal A, 2009, 364: 191[30] Abelló S, Bonilla A, Pérez-Ramírez J. Appl Catal A, 2009, 364: 191

    31. [31] Garcia-Martinez J, Li K H, Krishnaiah G. Chem Commun, 2012, 48: 11841[31] Garcia-Martinez J, Li K H, Krishnaiah G. Chem Commun, 2012, 48: 11841

    32. [32] Verboekend D, Perez-Ramirez J. Chem Eur J, 2011, 17: 1137[32] Verboekend D, Perez-Ramirez J. Chem Eur J, 2011, 17: 1137

    33. [33] Li B, Sun B, Qian X F, Li W, Wu Z X, Sun Z K, Qiao M H, Duke M, Zhao D Y. J Am Chem Soc, 2013, 135: 1181[33] Li B, Sun B, Qian X F, Li W, Wu Z X, Sun Z K, Qiao M H, Duke M, Zhao D Y. J Am Chem Soc, 2013, 135: 1181

    34. [34] Cundy C S, Cox P A. Microporous Mesoporous Mater, 2005, 82: 1[34] Cundy C S, Cox P A. Microporous Mesoporous Mater, 2005, 82: 1

    35. [35] Yoo W C, Zhang X Y, Tsapatsis M, Stein A. Microporous Mesoporous Mater, 2012, 149: 147[35] Yoo W C, Zhang X Y, Tsapatsis M, Stein A. Microporous Mesoporous Mater, 2012, 149: 147

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  • 发布日期:  2015-06-20
  • 收稿日期:  2014-10-30
  • 网络出版日期:  2014-12-10
通讯作者: 陈斌, bchen63@163.com
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