Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

Citation: Xiu-nan Yin, Jing Wang, Jian-jun Zhou, Lin Li. Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation[J]. Chinese Journal of Polymer Science, 2015, 33(12): 1721-1729. doi: 10.1007/s10118-015-1726-8 shu

Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

1.
Beijing Key Laboratory of Energy Conversion and Storage Materials, Academy of Chemistry, Beijing Normal University, Beijing 100875, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China(No.21434003), National Program on Key Basic Research Project(973 Program)(No.2011CB605605), National Science and Technology Major Project of the Ministry of Science and Technology of China(No.2013ZX09J13110-11B), the Fundamental Research Funds for the Central Universities and the Program for Changjiang Scholars and Innovative Research Teams in Universities.

摘要: In this manuscript, an easy method of anchoring Au nanoparticles onto a polypropylene(PP) membrane to prepare a composite Au-PP membrane with catalytic activity was demonstrated. The surface of the PP membrane was first modified with a primary amine by mussel-inspired dopamine polymerization. Then, the modified PP membrane was used to reduce chloroauric acid to anchor Au nanoparticles onto the surface, forming a Au-PP membrane. The surface morphology and composition of the modified PP membrane were characterized with SEM, ATR-FTIR and XPS. The catalytic activity of the Au-PP membrane was also evaluated by the degradation of a model dye solution of methylene blue. The fabricated membrane shows excellent catalytic performance, and the catalytic activity can be effectively regenerated.

关键词:

English

Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

1.
Beijing Key Laboratory of Energy Conversion and Storage Materials, Academy of Chemistry, Beijing Normal University, Beijing 100875, China
Received Date: 22 May 2015
Revised Date: 11 July 2015
Available Online: 05 December 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China(No.21434003), National Program on Key Basic Research Project(973 Program)(No.2011CB605605), National Science and Technology Major Project of the Ministry of Science and Technology of China(No.2013ZX09J13110-11B), the Fundamental Research Funds for the Central Universities and the Program for Changjiang Scholars and Innovative Research Teams in Universities.

Abstract: In this manuscript, an easy method of anchoring Au nanoparticles onto a polypropylene(PP) membrane to prepare a composite Au-PP membrane with catalytic activity was demonstrated. The surface of the PP membrane was first modified with a primary amine by mussel-inspired dopamine polymerization. Then, the modified PP membrane was used to reduce chloroauric acid to anchor Au nanoparticles onto the surface, forming a Au-PP membrane. The surface morphology and composition of the modified PP membrane were characterized with SEM, ATR-FTIR and XPS. The catalytic activity of the Au-PP membrane was also evaluated by the degradation of a model dye solution of methylene blue. The fabricated membrane shows excellent catalytic performance, and the catalytic activity can be effectively regenerated.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

English

Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

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Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

English

Mussel-inspired Modification of Microporous Polypropylene Membranes for Functional Catalytic Degradation

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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