Magnetic Polymer Microsphere Stabilized Gold Nanocolloids as A Facilely Recoverable Catalyst

Han Zhang Xin-lin Yang

Citation:  Han Zhang, Xin-lin Yang. Magnetic Polymer Microsphere Stabilized Gold Nanocolloids as A Facilely Recoverable Catalyst[J]. Chinese Journal of Polymer Science, 2011, 29(3): 342-351. doi: 10.1007/s10118-011-1036-8 shu

Magnetic Polymer Microsphere Stabilized Gold Nanocolloids as A Facilely Recoverable Catalyst

摘要: Magnetically responsive hierarchical magnetite/silica/poly(ethyleneglycol dimethacrylate-co-4-vinylpyridine) (Fe3O4/SiO2/P(EGDMA-co-VPy)) tri-layer microspheres were used as stabilizers for gold metallic nanocolloids as a facilely recoverable catalyst with the reduction of 4-nitrophenol to 4-aminophenol as a model reaction. The magnetic microsphere stabilized gold metallic nanocolloids were prepared by in situ reduction of gold chloride trihydrate with borohydride as reductant via the stabilization effect of the pyridyl groups to gold nanoparticles on the surface of the outer shell-layer of the inorganic/polymer tri-layer microspheres.

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  • 发布日期:  2011-05-05
  • 收稿日期:  2010-04-15
  • 修回日期:  2010-05-18
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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