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Tetrazole-1-acetic acid as a ligand for copper-catalyzed N-arylation of imidazoles with aryl iodides under mild conditions

Feng-Tian Wu ,  Ping Liu ,  Xiao-Wei Ma ,  Jian-Wei Xie ,  Bin Dai

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Citation:  Feng-Tian Wu, Ping Liu, Xiao-Wei Ma, Jian-Wei Xie, Bin Dai. Tetrazole-1-acetic acid as a ligand for copper-catalyzed N-arylation of imidazoles with aryl iodides under mild conditions[J]. Chinese Chemical Letters, 2013, 24(10): 893-896. shu

Tetrazole-1-acetic acid as a ligand for copper-catalyzed N-arylation of imidazoles with aryl iodides under mild conditions

    • 通讯作者: Jian-Wei Xie,
  • 基金项目:

    This work was supported financially by the National Basic Research Program of China (973 Program, No. 2012CB722603)  (973 Program, No. 2012CB722603)

    the Start-Up Foundation for Young Scientists of Shihezi University (Nos. RCZX201012, RCZX201014, RCZX201015). (Nos. RCZX201012, RCZX201014, RCZX201015)

摘要: Tetrazole-1-acetic acid was found to serve as a superior ligand for CuI-catalyzed N-arylation of imidazoles with aryl iodides under a low catalyst loading (5 mol% of CuI). A variety of aryl iodides could be aminated to provide the N-arylated products in good to excellent yields without the need of an inert atmosphere.

English

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  • 收稿日期:  2013-05-03
  • 网络出版日期:  2013-05-22
通讯作者: 陈斌, bchen63@163.com
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