引用本文:
Yi Hua YANG, Yu Lin LI. The First Total Synthesis of Saurufuran B[J]. Chinese Chemical Letters,
2006, 17(10): 1287-1288.
Citation: Yi Hua YANG, Yu Lin LI. The First Total Synthesis of Saurufuran B[J]. Chinese Chemical Letters, 2006, 17(10): 1287-1288.
Citation: Yi Hua YANG, Yu Lin LI. The First Total Synthesis of Saurufuran B[J]. Chinese Chemical Letters, 2006, 17(10): 1287-1288.
The First Total Synthesis of Saurufuran B
摘要:
First total synthesis of saurufuran B 1, a furanoditerpene, from (E, E)-farnesol 2 and citraconic anhydride 3 through thirteen steps is described. Our work involves two key steps:(1)High regioselective alkylation of 2-(tert-butyldimethylsiloxy)-4-methylfuran 6 with allylic iodides 5 in the presence of silver trifluoroacetate1 and (2) Conversion of substituted γ-lactone 7 into furan derivative 82.
English
The First Total Synthesis of Saurufuran B
Abstract:
First total synthesis of saurufuran B 1, a furanoditerpene, from (E, E)-farnesol 2 and citraconic anhydride 3 through thirteen steps is described. Our work involves two key steps:(1)High regioselective alkylation of 2-(tert-butyldimethylsiloxy)-4-methylfuran 6 with allylic iodides 5 in the presence of silver trifluoroacetate1 and (2) Conversion of substituted γ-lactone 7 into furan derivative 82.
-
Key words:
- Saurufuran B
- / first total synthesis
- / furanoditerpene
- / regioselective alkylation
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 0
- HTML全文浏览量: 0
下载:
