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Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains

Li Zeng PENG ,  Feng Zhi ZHANG ,  Tian Sheng MEI ,  Yu Lin LI

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引用本文: Li Zeng PENG,  Feng Zhi ZHANG,  Tian Sheng MEI,  Yu Lin LI. Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains[J]. Chinese Chemical Letters, 2003, 14(9): 889-892. shu
Citation:  Li Zeng PENG,  Feng Zhi ZHANG,  Tian Sheng MEI,  Yu Lin LI. Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains[J]. Chinese Chemical Letters, 2003, 14(9): 889-892. shu

Studies on the Model Synthesis of the Brassinolide and Dolicholide Side Chains

  • National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000

  • 基金项目:

    This work was financially supported by the National Natural Science Foundation of China (Grant No.20072012) and the Special Research Grant for Doctoral Sites in Chinese Universities (Grant No.20010730001).

摘要: A stereoselective synthesis of brassinolide and dolicholide, which involves construction of the side chain enantiomers by a highly stereoselective aldol reaction of aldehyde 5 with the anion of α-silyloxy ketone 6 is described.

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  • 收稿日期:  2002-09-09
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