引用本文:
Dong Mei HAN, Xun Tian JIANG, Jian Hong CHEN, Bin WANG, Dong Lu BAI. Diastereoselective Michael Addition of (4'S)-Ethyl-3-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl) acrylate with Furyl Lithium[J]. Chinese Chemical Letters,
2001, 12(5): 403-406.
Citation: Dong Mei HAN, Xun Tian JIANG, Jian Hong CHEN, Bin WANG, Dong Lu BAI. Diastereoselective Michael Addition of (4'S)-Ethyl-3-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl) acrylate with Furyl Lithium[J]. Chinese Chemical Letters, 2001, 12(5): 403-406.
Citation: Dong Mei HAN, Xun Tian JIANG, Jian Hong CHEN, Bin WANG, Dong Lu BAI. Diastereoselective Michael Addition of (4'S)-Ethyl-3-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl) acrylate with Furyl Lithium[J]. Chinese Chemical Letters, 2001, 12(5): 403-406.
Diastereoselective Michael Addition of (4'S)-Ethyl-3-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl) acrylate with Furyl Lithium
摘要:
Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity.The diastereoselectivity was not affected by the configuration of the double bond in 2.
English
Diastereoselective Michael Addition of (4'S)-Ethyl-3-(2',2'-Dimethyl-1',3'-dioxolan-4'-yl) acrylate with Furyl Lithium
Abstract:
Michael addition of the chiral α,β-unsaturated ester 2 with furyl lithium proceeded in syn manner with excellent diastereoselectivity.The diastereoselectivity was not affected by the configuration of the double bond in 2.
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Key words:
- Michael addition
- / configuration determination
- / syn addition.
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