引用本文:
Zhuo Bin YUAN, Zhi Ru MA. A Novel and Convenient Assay for the Determination of OH Produced by Fenton Reaction[J]. Chinese Chemical Letters,
1998, 9(6): 569-571.
Citation: Zhuo Bin YUAN, Zhi Ru MA. A Novel and Convenient Assay for the Determination of OH Produced by Fenton Reaction[J]. Chinese Chemical Letters, 1998, 9(6): 569-571.
Citation: Zhuo Bin YUAN, Zhi Ru MA. A Novel and Convenient Assay for the Determination of OH Produced by Fenton Reaction[J]. Chinese Chemical Letters, 1998, 9(6): 569-571.
A Novel and Convenient Assay for the Determination of OH Produced by Fenton Reaction
摘要:
A novel, simple and convenient method for the determination of hydroxyl radicals is established. Hydroxyl radicals produced by Fenton reaction is trapped by spin trap reagent phenyl-t-butyl nitrone (PBN), and the free radical adduct of PBN can be detected by single sweep oscillopolarography, with its second order derivative cathodic wave at -0.52V vs SCE. The optimum experimental conditions for the determination is discussed, and the scavenging effects of some compounds on OH was also studied.
English
A Novel and Convenient Assay for the Determination of OH Produced by Fenton Reaction
Abstract:
A novel, simple and convenient method for the determination of hydroxyl radicals is established. Hydroxyl radicals produced by Fenton reaction is trapped by spin trap reagent phenyl-t-butyl nitrone (PBN), and the free radical adduct of PBN can be detected by single sweep oscillopolarography, with its second order derivative cathodic wave at -0.52V vs SCE. The optimum experimental conditions for the determination is discussed, and the scavenging effects of some compounds on OH was also studied.
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Key words:
- hydroxyl radicals
- / Fenton reaction
- / spin trap reagent PBN
- / electrochemical method
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