引用本文:
Qing WU, Ze Jian LU, Fang Cheng TANG. SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF NORBORNENE-ETHYLENE BLOCK COPOLYMER[J]. Chinese Chemical Letters,
1995, 6(10): 907-910.
Citation: Qing WU, Ze Jian LU, Fang Cheng TANG. SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF NORBORNENE-ETHYLENE BLOCK COPOLYMER[J]. Chinese Chemical Letters, 1995, 6(10): 907-910.
Citation: Qing WU, Ze Jian LU, Fang Cheng TANG. SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF NORBORNENE-ETHYLENE BLOCK COPOLYMER[J]. Chinese Chemical Letters, 1995, 6(10): 907-910.
SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF NORBORNENE-ETHYLENE BLOCK COPOLYMER
摘要:
Transformation of living ring-opening metathesis polymerization (ROMP) into coordination polymerization by converting the titanacyclobutane attached to a polynorbornene (polyNBE) chain into titanocene alkoxide has been used to the synthesis of poly(NBE-b-ethylene).The copolymerization product,after being extracted by CH2Cl2 to separate the NBE homopolymer,exhibits the Tg of polyNBE segments and Tm of polyethylene segments by DSC measurement.
English
SYNTHESIS AND PRELIMINARY CHARACTERIZATION OF NORBORNENE-ETHYLENE BLOCK COPOLYMER
Abstract:
Transformation of living ring-opening metathesis polymerization (ROMP) into coordination polymerization by converting the titanacyclobutane attached to a polynorbornene (polyNBE) chain into titanocene alkoxide has been used to the synthesis of poly(NBE-b-ethylene).The copolymerization product,after being extracted by CH2Cl2 to separate the NBE homopolymer,exhibits the Tg of polyNBE segments and Tm of polyethylene segments by DSC measurement.
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