引用本文:
Qian LIU, Ji Yu Guo, Yan Qing XU, Hong Ju FANG, Xiao Tian LIANG. SYEREOSELECTIVE TOTAL SYNTHESIS OF DEHYDROBAIMUXINOL AND ISOBAIMUXINOL[J]. Chinese Chemical Letters,
1991, 2(6): 425-428.
Citation: Qian LIU, Ji Yu Guo, Yan Qing XU, Hong Ju FANG, Xiao Tian LIANG. SYEREOSELECTIVE TOTAL SYNTHESIS OF DEHYDROBAIMUXINOL AND ISOBAIMUXINOL[J]. Chinese Chemical Letters, 1991, 2(6): 425-428.
Citation: Qian LIU, Ji Yu Guo, Yan Qing XU, Hong Ju FANG, Xiao Tian LIANG. SYEREOSELECTIVE TOTAL SYNTHESIS OF DEHYDROBAIMUXINOL AND ISOBAIMUXINOL[J]. Chinese Chemical Letters, 1991, 2(6): 425-428.
SYEREOSELECTIVE TOTAL SYNTHESIS OF DEHYDROBAIMUXINOL AND ISOBAIMUXINOL
摘要:
The first synthesis of dehydrobaimuxinol 1 in seven steps and isobaimuxinol 2 by further hydrogenation has been achieved in a stereoselective manner from (-)-carvone.The key step is the regiospecific and exclusive mono-substitution at C-4 to give the enone intermediate 8.The absolute configurations of these two natural products[2] have been unambiguously established by the present synthesis.
English
SYEREOSELECTIVE TOTAL SYNTHESIS OF DEHYDROBAIMUXINOL AND ISOBAIMUXINOL
Abstract:
The first synthesis of dehydrobaimuxinol 1 in seven steps and isobaimuxinol 2 by further hydrogenation has been achieved in a stereoselective manner from (-)-carvone.The key step is the regiospecific and exclusive mono-substitution at C-4 to give the enone intermediate 8.The absolute configurations of these two natural products[2] have been unambiguously established by the present synthesis.
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