引用本文:
聂旭文, 崔燕军, 唐小真. 一种无机有机聚合物中间体——六(甲基丙烯酸羟乙酯)三聚膦腈的合成[J]. 应用化学,
2003, 20(4): 385-387.
Citation: NIE XU-Wen, CUI Yan-Jun, TANG Xiao-Zhen. Synthesis of Hexa (2-hydroxyethyl methacrylate) cyclotriphosphazene[J]. Chinese Journal of Applied Chemistry, 2003, 20(4): 385-387.
Citation: NIE XU-Wen, CUI Yan-Jun, TANG Xiao-Zhen. Synthesis of Hexa (2-hydroxyethyl methacrylate) cyclotriphosphazene[J]. Chinese Journal of Applied Chemistry, 2003, 20(4): 385-387.
一种无机有机聚合物中间体——六(甲基丙烯酸羟乙酯)三聚膦腈的合成
摘要:
1965年Allcock等[1]首次报道六氯三聚膦腈(HCCP)热开环聚合制备聚二氯膦腈(PDCP)以来,大量的研究工作集中在引入不同的侧链以合成具有各种性能的无机有机高分子。
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关键词:
- 六氯三聚膦腈
- / 六(甲基丙烯酸羟乙酯)三聚膦腈
English
Synthesis of Hexa (2-hydroxyethyl methacrylate) cyclotriphosphazene
Abstract:
Hexa (2-hydroxyethyl methacrylate) cyclotriphosphazene (HHMP) was synthesized from 2-hydroxyethyl methacrylate and hexachlorocyclotriphosphazene through nucleophilic substitution reaction in the presence of cuprous chloride as a catalyst.Raman,FTIR and NMR techniques were used to characterize and confirm the structure of the product compound.
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