引用本文:
陈立功, 张素峰, 王东华, 孟祎, 古险峰, 宋芸. 松树叶蜂性信息素的合成[J]. 应用化学,
2001, 18(8): 623-626.
Citation: CHEN Li Gong, ZHANG Su-Feng, WANG Dong-Hua, MENG Yi, GU Xian-Feng, SONG Yun. Synthesis of Sex Pheromone of Diprion pini[J]. Chinese Journal of Applied Chemistry, 2001, 18(8): 623-626.
Citation: CHEN Li Gong, ZHANG Su-Feng, WANG Dong-Hua, MENG Yi, GU Xian-Feng, SONG Yun. Synthesis of Sex Pheromone of Diprion pini[J]. Chinese Journal of Applied Chemistry, 2001, 18(8): 623-626.
松树叶蜂性信息素的合成
摘要:
以丙二酸二乙酯为原料,经己基化、甲基化、水解、脱羧、还原、溴化合成了2-甲基溴辛烷;以乙酰丙酮为原料,经甲基化、单羰基保护得到了3-甲基-4-(4-甲基-1,3-二氧戊环)-2-戊酮.它们是合成松树叶蜂性信息素的关键中间体.
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关键词:
- 松树叶蜂
- / 性信息素
- / 二甲基十三醇
- / 甲基溴辛烷
- / 甲基(甲基二氧戊环)戊酮
English
Synthesis of Sex Pheromone of Diprion pini
Abstract:
1-Bromo-2-methyloctane was obtained from diethyl malonate through hexylation, methylation, hydrolysis, decarboxylation, reduction, and bromination while 3-methyl 4-(4-methyl-1,3-dioxolan)-2-pentanone was synthesized from acetylacetone through methylation, protection of single carboxyl group. The above two compounds are the key intermediates for the synthesis of sex pheromone of Diprion pini.
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