引用本文:
江涛, 曾繁涤. 聚8,8'-二羟基-5,5'-偶氮苯二喹啉金属螯合物的合成及荧光性质[J]. 应用化学,
2000, 17(3): 334-336.
Citation: JIANG Tao, ZENG Fan-Di. Synthesis and Fluorescence Property of Polymeric 8,8'-Dihydroxy 5,5'-azobenzolbiquinoline Metal Chelates[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 334-336.
Citation: JIANG Tao, ZENG Fan-Di. Synthesis and Fluorescence Property of Polymeric 8,8'-Dihydroxy 5,5'-azobenzolbiquinoline Metal Chelates[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 334-336.
聚8,8'-二羟基-5,5'-偶氮苯二喹啉金属螯合物的合成及荧光性质
English
Synthesis and Fluorescence Property of Polymeric 8,8'-Dihydroxy 5,5'-azobenzolbiquinoline Metal Chelates
Abstract:
Two polym eric chelates of 8-dihydroxyquinoline synthesized from biquinoline monomer with zinc acetate and copper acetate, respectively, are reported. The effects of reactant amount, reaction time on the yield of products have been studied. The IR and photoluminescence(PL) emission spectra of monomer and chelates have been recorded. The uniform films of polymerica zobenzolbiquino line metal chelates were self-assembled on hydroxy-functional surfaces by alternately dipping in DMF solution of metal acetate and monomer.
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Key words:
- hydroxy quinoline
- / metal chelate
- / synthesis
- / fluorescence
- / self-assembled thin film
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