引用本文:
唐洁渊, 高锋, 章文贡, 王文. 电化学聚合漆酚-铕配合物的合成及性质[J]. 应用化学,
2000, 17(3): 325-327.
Citation: TANG Jie-Yuan, GAO Feng, ZHANG Wen-Gong, WANG Wen. Synthesis and Property of Polymeric Complex of Electropolyurushiol(EPU) with Europium[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 325-327.
Citation: TANG Jie-Yuan, GAO Feng, ZHANG Wen-Gong, WANG Wen. Synthesis and Property of Polymeric Complex of Electropolyurushiol(EPU) with Europium[J]. Chinese Journal of Applied Chemistry, 2000, 17(3): 325-327.
电化学聚合漆酚-铕配合物的合成及性质
English
Synthesis and Property of Polymeric Complex of Electropolyurushiol(EPU) with Europium
Abstract:
Title polymeric complex(EPU-Eu(Ⅲ)) was obtained from triisobutoxy euro-pium Eu(C3H7O)3 with electropolyurushiol in isobutyl alcohol. The structure and property of the complex were characterized by FT-IR, XPS, DMTA, AES, TG-DTA and fluorescence spectrophotometry. The complex with Eu(Ⅲ) content reached up to 9.6% was insoluble in most organic solvents. Its electric resistance was 1.25×105 MΩ(that of EPU was 7.90×104 MΩ). Its Tg and thermal resistance was considerably greater than that of EPU.
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Key words:
- electrochemical polymerization
- / urushiol
- / europium
- / polymeric complex
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