引用本文:
刘兴泉, 陈文凯, 梁国华, 吴玉塘, 于作龙. 合成气低温液相催化制甲醇和甲酸甲酯铜基催化剂体系研究Ⅰ.氯化亚铜催化剂体系中各种因素的影响[J]. 应用化学,
1999, 16(4): 86-88.
Citation: Liu Xingquan, Chen Wenkai, Liang Guohua, Wu Yutang, Yu Zuolong. Preparation of Methanol and Methyl formate from Syngas over Copper-based Catalysts at Low Temperature Ⅰ.With CuCl Catalyst System[J]. Chinese Journal of Applied Chemistry, 1999, 16(4): 86-88.
Citation: Liu Xingquan, Chen Wenkai, Liang Guohua, Wu Yutang, Yu Zuolong. Preparation of Methanol and Methyl formate from Syngas over Copper-based Catalysts at Low Temperature Ⅰ.With CuCl Catalyst System[J]. Chinese Journal of Applied Chemistry, 1999, 16(4): 86-88.
合成气低温液相催化制甲醇和甲酸甲酯铜基催化剂体系研究Ⅰ.氯化亚铜催化剂体系中各种因素的影响
English
Preparation of Methanol and Methyl formate from Syngas over Copper-based Catalysts at Low Temperature Ⅰ.With CuCl Catalyst System
Abstract:
The catalytic activity of cuprous chloride with promotor H for synthesis of methanol and methyl formate(MF) at low temperature in a batched slurry reactor have been investigated by examining the effects of pressure, temperature and catalyst concentration as well as promotor concentration. The results indicate that the catalytic activity increases as the reaction pressure is raised and decreases with the increase of the reaction temperature. Both the catalytic activity and methanol selectivity increase, but MF selectivity decreases with the increases of the catalyst concentration. Addition of the promoter increases the activity of the catalyst with considerable decrease of the MF selectivity.
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Key words:
- methanol
- / methyl formate
- / synthesis
- / cuprous chloride
- / syngas
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