引用本文:
阎雁, 佟珊玲, 郭魁, 郑国栋, 甄开吉, 方赤光, 常新. 金属卟啉催化氧化萘酚Ⅰ.2-羟基-1,4-萘醌的制备[J]. 应用化学,
1999, 16(4): 28-32.
Citation: Yan Yan, Tong Shanling, Guo Kui, Zheng Guodong, Zhen Kaiji, Fang Chiguang, Chang Xin. Catalytic Oxidation of Naphthol over Metalloporphyrins Ⅰ.Synthesis of 2-Hydroxy-1,4-naphthaqinone[J]. Chinese Journal of Applied Chemistry, 1999, 16(4): 28-32.
Citation: Yan Yan, Tong Shanling, Guo Kui, Zheng Guodong, Zhen Kaiji, Fang Chiguang, Chang Xin. Catalytic Oxidation of Naphthol over Metalloporphyrins Ⅰ.Synthesis of 2-Hydroxy-1,4-naphthaqinone[J]. Chinese Journal of Applied Chemistry, 1999, 16(4): 28-32.
金属卟啉催化氧化萘酚Ⅰ.2-羟基-1,4-萘醌的制备
English
Catalytic Oxidation of Naphthol over Metalloporphyrins Ⅰ.Synthesis of 2-Hydroxy-1,4-naphthaqinone
Abstract:
Title compound(HNQ) has been catalytically synthesized from 1- and 2-naphthol over metalloporphyrins in methanol solution of NaOH using hydroperoxide as an oxidant with maximum yield of 40% and 57%, respectively. The method is characteristic of low reaction temperature, high conversion of naphthol, strong alkali medium, easy operation and high yield of the products.
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Key words:
- hydroxy-naphthaqinone
- / preparation
- / nathphol
- / metalloporphyrin
- / catalytic oxidation
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