引用本文:
章伟光, 唐宁, 甘新民, 谭民裕. 稀土与含硫有机配体配合物的研究Ⅳ.轻稀土元素与3-苯基-5-(呋喃-2)吡唑啉二硫代甲酸固体配合物的合成及性质[J]. 应用化学,
1992, 9(3): 83-86.
Citation: Zhang Weiguang, Tang Ning, Gan Xinmin, Tan Minyu. STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE[J]. Chinese Journal of Applied Chemistry, 1992, 9(3): 83-86.
Citation: Zhang Weiguang, Tang Ning, Gan Xinmin, Tan Minyu. STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE[J]. Chinese Journal of Applied Chemistry, 1992, 9(3): 83-86.
稀土与含硫有机配体配合物的研究Ⅳ.轻稀土元素与3-苯基-5-(呋喃-2)吡唑啉二硫代甲酸固体配合物的合成及性质
English
STUDIES ON THE COMPLEXES OF RARE EARTH WITH SULPHUR CONTAINING ORGANIC LIGANDS Ⅳ.SYNTHESIS AND CHARACTERIZATION OF SOLID COMPLEXES OF LIGHT RARE EARTH WITH 3-PHENYL-5-(FURYL-2)PYRAZOLINE DITHIOFORMATE
Abstract:
Five solid complexes of rare earth with 3-phenyl-5-(furyl-2)pyrazoline dithioformate RE(S2CNC13H11NO)3·nH2O(RE=La, Pr, Nd, Sm, Eu; n=2,4) have been synthesized in dry N2 atmosphere and characterized by elemental analyses, IR spectra, molar con uctance, thermal analyses and fluorescence spectra. The results show that ligands are ccordinated to RE ion through two sulphur atom donors.
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Key words:
- La
- / Pr
- / Nd
- / Sm
- / Eu
- / 3-phenyl-5-(furyl) pyrazoline dithioformate
- / complex
- / synthesis
- / physical property
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