引用本文:
高占先, 张爱丽, 于净, 周科衍. 1-丁烯齐聚反应——Ⅰ.六氟代戊二酮合镍/乙氧基二乙基铝的催化作用[J]. 应用化学,
1987, 4(1): 40-43.
Citation: Gao Zhanxian, Zhang Aili, Yu Jing, Zhou Keyan. OLIGOMERIZATION REACTION OF 1-BUTENE Ⅰ.CATALYTIC BEHAVIOR 0F 1,1,1,5,5,5-HEXAFLURO-2,4-PEN-TADIONATO-NICKEL/DIETHYL ALUMINIUM ETHOXIDE[J]. Chinese Journal of Applied Chemistry, 1987, 4(1): 40-43.
Citation: Gao Zhanxian, Zhang Aili, Yu Jing, Zhou Keyan. OLIGOMERIZATION REACTION OF 1-BUTENE Ⅰ.CATALYTIC BEHAVIOR 0F 1,1,1,5,5,5-HEXAFLURO-2,4-PEN-TADIONATO-NICKEL/DIETHYL ALUMINIUM ETHOXIDE[J]. Chinese Journal of Applied Chemistry, 1987, 4(1): 40-43.
1-丁烯齐聚反应——Ⅰ.六氟代戊二酮合镍/乙氧基二乙基铝的催化作用
摘要:
本文考察了1,1,1,5,5,5-六氟代戊二酮合镍/乙氧基二乙基铝催化1-丁烯的齐聚反应,证明它是1-丁烯线性齐聚反应的催化体系,同时也观察到了此体系对1-丁烯的异构化反应和加氢反应也有催化作用。
English
OLIGOMERIZATION REACTION OF 1-BUTENE Ⅰ.CATALYTIC BEHAVIOR 0F 1,1,1,5,5,5-HEXAFLURO-2,4-PEN-TADIONATO-NICKEL/DIETHYL ALUMINIUM ETHOXIDE
Abstract:
In this paper, the oligomerization reaction of 1-butene has been studied using 1,1,1,5,5,5-haxafluro-2,4-pentadionato-nickel/diethyl aluminium ethoxide, (hfacac)2Ni/Et2AlOEt, as catalyst. Results showed that (hfacac)2Ni/Et2AlOEt is an efficient catalyst for linear oligomerization of 1-butene and also cata1yzes isomerization and hydrogenation of 1-butene.
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