Citation:
XU Hui, CAO Xinyu, LI Ze, CAO Ming, DAI Daorong, XIE Ping, ZHANG Rongben. A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*[J]. Chinese Journal of Polymer Science,
1998, 16(3): 253-260.
A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
摘要:
A novel supramolecular polysiloxane clathrate, POS/C, has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA ) , one kindof Schiff base liquid crystal molecule, within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM), differ-ential scanning calorimetry (DSC), infrared spectroscopy (IR), atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.
English
A NOVEL SUPRAMOLECULAR CLATHRATE OF RODLIKE p-BUTOXYBENZYLIDENE-p′-DODECOXYANILINE TRAPPED WITHIN POLYORGANOSILOXANE PORE*
Abstract:
A novel supramolecular polysiloxane clathrate, POS/C, has been preparedby in-situ encapsulating rodlike p-butoxybenzylidene-p ' - dodecoxyaniline (BBDA ) , one kindof Schiff base liquid crystal molecule, within the pore of polyorganosiloxane (POS) whichis prepared by hydrosilylation coupling reaction of polyvinylsilsesquioxane (Vi- T ) withtetramethyldisiloxane (H-MM). Investigation by polarized light microscopy (PLM), differ-ential scanning calorimetry (DSC), infrared spectroscopy (IR), atomic force microscopy (AFM) and molecular simulation gives a preliminary support to the existence of the title supramolecular clathrate.
扫一扫看文章
计量
- PDF下载量: 0
- 文章访问数: 0
- HTML全文浏览量: 0
下载:
