EFFECT OF IRRADIATION TEMPERATURE ON GENERAL EQUATION OF SOL FRACTION-DOSE RELATIONSHIP FOR FLUOROPOLYMERS

ZHANG Wanxi XU Jun

Citation:  ZHANG Wanxi, XU Jun. EFFECT OF IRRADIATION TEMPERATURE ON GENERAL EQUATION OF SOL FRACTION-DOSE RELATIONSHIP FOR FLUOROPOLYMERS[J]. Chinese Journal of Polymer Science, 1992, 10(1): 94-97. shu

EFFECT OF IRRADIATION TEMPERATURE ON GENERAL EQUATION OF SOL FRACTION-DOSE RELATIONSHIP FOR FLUOROPOLYMERS

摘要: In this paper, the effect of irradiation temperature on sol fraction-dose relationship of tluoropolymers was studied. It was found that the increasing of irradiation temperature can result in the decreasing of β value of fluoropolymer, which increases the crosslinking probability of fluoropolymer. The relationship between crosslinking parameter βand irradiation temperature (Ti)of fluoropolymer is established as follows: β=2.2×10-3 Tg+4×10-4(Tg-Ti)+0.206. values of some tluoropolymers calculated from the above expression are in agreement with the experimental values.

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  • 发布日期:  1992-03-20
  • 收稿日期:  1991-01-15
通讯作者: 陈斌, bchen63@163.com
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    沈阳化工大学材料科学与工程学院 沈阳 110142

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