Citation:
BA Hengfei, PENG Xinsheng, CHEN Donglin, WANG Fosong. SYNTHESIS AND NMR CHARACTERIZATION OF PRECURSORS OF EPOXY NETWORK AS POLYMER HOST FOR SOLID ELECTROLYTE*[J]. Chinese Journal of Polymer Science,
1992, 10(1): 32-43.
SYNTHESIS AND NMR CHARACTERIZATION OF PRECURSORS OF EPOXY NETWORK AS POLYMER HOST FOR SOLID ELECTROLYTE*
摘要:
To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether of polyethylene glycols as precursors of the system were synthesized by a two-step process. The presumed structure of the product was characterized, by 13C, 1H NMR and IR spectroscopy. It was found that a side-reaction occurred between the secondary hydroxyl group of PEG-chlorohydrin and epichlorohydrin in some degree,resulting in a by-product containing-CH2Cl side group.By selecting a characteristic signal,which is undistorted by the increase in the length of CH2CH2-O segment,a 1H NMR approach of determining the equivalent epoxy weight (EEW) was proposed.The method is valid to specimens even though the EEW is as high as 2,000.The examination of the specimens by DSC showed that epoxidation greatly depressed the crystallinity of the PEG's,whereas the Tg was raised.
English
SYNTHESIS AND NMR CHARACTERIZATION OF PRECURSORS OF EPOXY NETWORK AS POLYMER HOST FOR SOLID ELECTROLYTE*
Abstract:
To raise the room temperature ionic conductivity and improve the mechanical strength of a PEO-based polymer electrolyte, a noncrystalline two-component epoxy electrolyte system has been prepared. The diglycidyl ether of polyethylene glycols as precursors of the system were synthesized by a two-step process. The presumed structure of the product was characterized, by 13C, 1H NMR and IR spectroscopy. It was found that a side-reaction occurred between the secondary hydroxyl group of PEG-chlorohydrin and epichlorohydrin in some degree,resulting in a by-product containing-CH2Cl side group.By selecting a characteristic signal,which is undistorted by the increase in the length of CH2CH2-O segment,a 1H NMR approach of determining the equivalent epoxy weight (EEW) was proposed.The method is valid to specimens even though the EEW is as high as 2,000.The examination of the specimens by DSC showed that epoxidation greatly depressed the crystallinity of the PEG's,whereas the Tg was raised.
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