Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

Citation: LI Chao, MENG Su-Qin, LAN Mei-Ying, YU Ying-Hua, CHEN Jian-Xin, ZHANG Zhi-Chun. Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)[J]. Chinese Journal of Structural Chemistry, 2014, 33(2): 289-293. shu

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

1.
a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

通讯作者: CHEN Jian-Xin,

基金项目:
Supported by the Natural Science Foundation of Fujian Province (2010J01026) (2010J01026)

the Ministry of Education of China (No.208066) (No.208066)

the Education Department of Fujian Province (JA07029) (JA07029)

the State Key Laboratory of Structural Chemistry (No.20130013) (No.20130013)

摘要: The title complex bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methylenyl]-2-naphthalenola-to-N,O}nickel has been synthesized by the reaction of 1-[[(3-ethyl-6-methyl-2-pyridinyl) imino] methylenyl]-2-naphthalenol with Ni(CH₃COO)₂·4H₂O, and characterized by IR spectrum and single-crystal X-ray diffraction analysis. The crystal belongs to the orthorhombic system, space group Pbca with a=11.100(2), b=15.900(3), c=18.000(4) Å, V=3176.8(11) Å³, C₃₈H₃₄N₄NiO₂, M_r=637.40, Z=4, D_c=1.333 g/cm³, μ=0.651 mm^-1, F(000)=1336, the final R=0.0783 and wR=0.2119. This title compound was investigated for the catalytic behavior towards norbornene (NB) vinyl addition polymerization. And the complex exhibited good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.

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English

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

1.
a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: CHEN Jian-Xin,

Received Date: 02 June 2013
Fund Project:

Abstract: The title complex bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methylenyl]-2-naphthalenola-to-N,O}nickel has been synthesized by the reaction of 1-[[(3-ethyl-6-methyl-2-pyridinyl) imino] methylenyl]-2-naphthalenol with Ni(CH₃COO)₂·4H₂O, and characterized by IR spectrum and single-crystal X-ray diffraction analysis. The crystal belongs to the orthorhombic system, space group Pbca with a=11.100(2), b=15.900(3), c=18.000(4) Å, V=3176.8(11) Å³, C₃₈H₃₄N₄NiO₂, M_r=637.40, Z=4, D_c=1.333 g/cm³, μ=0.651 mm^-1, F(000)=1336, the final R=0.0783 and wR=0.2119. This title compound was investigated for the catalytic behavior towards norbornene (NB) vinyl addition polymerization. And the complex exhibited good catalytic activity to catalyze norbornene polymerization using MAO as a cocatalyst.

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

通讯作者: CHEN Jian-Xin,

English

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

Corresponding author: CHEN Jian-Xin,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

通讯作者: CHEN Jian-Xin,

English

Synthesis, Structure and Norbornene Polymerization Catalyzed by Bis{1-[[(3-ethyl-6-methyl-2-pyridinyl)imino]methyl-enyl]-2-naphthalenolato-N,O}nickel(Ⅱ)

Corresponding author: CHEN Jian-Xin,

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

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