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固体氧化物直接碳燃料电池阳极反应过程分析

刘国阳 ,  周安宁 ,  张亚婷 ,  蔡江涛 ,  党永强 ,  邱介山

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引用本文: 刘国阳, 周安宁, 张亚婷, 蔡江涛, 党永强, 邱介山. 固体氧化物直接碳燃料电池阳极反应过程分析[J]. 燃料化学学报, 2015, 43(9): 1100-1105. shu
Citation:  LIU Guo-yang, ZHOU An-ning, ZHANG Ya-ting, CAI Jiang-tao, DANG Yong-qiang, QIU Jie-shan. Analysis of the reaction process in solid oxide direct carbon fuel cell anode[J]. Journal of Fuel Chemistry and Technology, 2015, 43(9): 1100-1105. shu

固体氧化物直接碳燃料电池阳极反应过程分析

    通讯作者: 周安宁,教授,Tel:029-85583549,E-mail:zhouanning2004@aliyun.com.cn。
  • 基金项目:

    国家自然科学基金(21276207) (21276207)

    NSFC-新疆联合基金重点项目(U1203292) (U1203292)

    陕西省自然科学基础研究计划(2014JM2043)。 (2014JM2043)

摘要: 以氧化钇稳定的氧化锆(YSZ)为电解质组装成直接碳燃料电池(DCFC),分别以活性炭(AC)、石墨(G)、神府半焦(SC)作为DCFC燃料,研究了碳燃料的特性、电池操作温度以及阳极反应气氛等对DCFC阳极反应过程的影响。结果表明,三种碳燃料在空气、CO2气氛中氧化反应活性顺序为AC > SC > G,当三种碳材料作为DCFC燃料时,活性炭作为燃料的DCFC性能最好,半焦燃料次之,石墨作为燃料的DCFC性能最差,而且燃料反应活性与其表面含氧官能团、孔隙结构有关;DCFC的阳极反应过程存在碳燃料直接氧化为CO2、CO2与C反应转化为CO,以及CO氧化为CO2等。

English

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  • 收稿日期:  2015-02-05
  • 网络出版日期:  2015-05-07
通讯作者: 陈斌, bchen63@163.com
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