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Citation: Liu Erbao, Cai Ruifang, Huang Zu'en, Wei Jingde, Liu Zhi. Synthesis of Indenyl Phenyl Ytterbium(Ⅱ) Complexes[J]. Chinese Journal of Applied Chemistry, ;1995, 12(3): 73-75. shu

Synthesis of Indenyl Phenyl Ytterbium(Ⅱ) Complexes

Department of Chemistry, Fudan University, Shanghai 200433

Received Date: 30 August 1994
Revised Date: 2 December 1994

A complex of (C₆H₅)Yb(C₉H₇)·2THF(Ⅰ) has been synthesized by reacting a Grignard-type reagent C₆H₅YbI with KC₉H₇ in THF. It is a first Yb(Ⅱ) complex containing both π-ligand(indenyl) and σ-ligand(phenhyl). The similar reaction carried out in 1,2-dimethoxyethane(DME) gave (C₆H₅)Yb(C₉H₇)·DME(Ⅱ). Treatment of(Ⅰ) with diox-ane yielded (C₆H₅)Yb(C₉H₇)·THF·(1/2)Dioxane(Ⅲ). The three complexes(Ⅰ), (Ⅱ), and (Ⅲ) were analyzed by elemental analysis,IR,MS and ¹H NMR measurements.
- divalent ytterbium,
- indenyl,
- phenyl,
- complex,
- synthesis
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