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Citation: Ye Xiangrong, Hou Hongwei, Xin Xinquan. Studies on Solid State Reactions of Coordination Compounds LXVII. Constitution of M-S(M=Mo,W) Cluster Compound Films on the Copper Surface[J]. Chinese Journal of Applied Chemistry, ;1995, 12(2): 5-8. shu

Studies on Solid State Reactions of Coordination Compounds LXVII. Constitution of M-S(M=Mo,W) Cluster Compound Films on the Copper Surface

Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing 210093

Received Date: 21 July 1994
Revised Date: 5 December 1994

The M-S (M=Mo,W) cluster compound films on copper surfaces have been in-vestigated by FTIR, XPS and AES. The results show that Mo(W)-S-Cu bonds were formed by the reaction of Mo(W)S₄^2- with Cu₂O layer on copper surface. The films are com-posed of Mo(W),S,Cu and O,each with the valence of +6,-2,+1 and -2,respective-ly. A multimolecular layer structure of the films was verified. Only Cu and O were found on the film surface, MoS₄ or WS₂ units remain in the inner layers of the films. The thickness of the film was found to depend on the reaction time: the longer the time,the thicker the film. The color of the films is probably caused by a statistical distribution of various layers and the film is a complicated multicomponent and multilayer system.
- copper surface,
- molybdenum,
- tungsten,
- cluster compound film
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