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Citation: Shao Ruilian, Yang Minhua, Cheng Junran. Diastereoselective Synthesis of Asymmetrical 1,3,2-dioxaphosphorins and Their Biological Activity[J]. Chinese Journal of Applied Chemistry, ;1998, 15(2): 112-114. shu

Diastereoselective Synthesis of Asymmetrical 1,3,2-dioxaphosphorins and Their Biological Activity

Research Institute of Elemento Organic Chemistry Nankai University, State Key Laboratory of Elemento Organic Chemistry, Tianjin 300071

Received Date: 4 June 1997
Revised Date: 8 December 1997

Diastereomers of 2-oxo-2 substituted phenoxy-4-phenyl-5,5-dimethyl-1,3,2-dioxaphosphorin were synthesized. The synthetic methods, solvents and salts appeared to exhibit significant influences on the cis/trans ratio of the products. The isomerization between cis and trans cyclic phosphates was investigated. The preliminary bioassay indicated that some isomers have herbicidal and plant growth activity.
- dioxaphosphorin,
- stereoselective synthesis,
- diastereomer,
- biological activity
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