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Citation: Yang Luqin, Yan Shiping, Liao Daizheng, Jiang Zonghui, Wang Genglin, Shen Panwen. Syntheses,Magnetic Properties and Bioactivities of Transition Metal Binuclear Copmplexes[J]. Chinese Journal of Applied Chemistry, ;1994, 11(6): 37-40. shu

Syntheses,Magnetic Properties and Bioactivities of Transition Metal Binuclear Copmplexes

1.
Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 17 January 1994
Available Online: 25 April 1994
Fund Project:

Nine novel dinuclear complexes of transition metal ions with pentabenzimi-dazolylmethyl diethylene triamine are reported.The results of variable temperature magnetic susceptibility of the complexes indicated that an antiferromagnetic exchnge interaction exists between metal ions in dinuclear unit.Themagnitude of thespin interaction (J) of the complexes had the following sequence |J_{Cu²⁺,S=(1/2)}|>|J_Ni²⁺,S=1|>|J_{Co²⁺,S=(3/2)}|>|J_{Mn²⁺,S=(2/5)}|. The preliniinflry rexults of bioassay shwed that some complexeshd antitumor activities in vitro,regulating plant growth and fungicidal activities.
- transition metal complex,
- benzimidazole,
- magnetic property,
- bioactivity
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