Home

Citation: Meng Qingbo, Zhang Siyuan. Study on the Chemical Bonds of Rare Earth Ethylsulphate Complex Crystals[J]. Chinese Journal of Applied Chemistry, ;1994, 11(4): 69-73. shu

Study on the Chemical Bonds of Rare Earth Ethylsulphate Complex Crystals

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 27 September 1993
Available Online: 19 April 1994
Fund Project:

From the structure date of the rare earth ethylsulphates RE(C₂H₅SO₄)₃·9H₂O (RE=La→Lu,except Pm),their efficient valence electrons,efficient valence densities and average coordinatiOn numbers of bonds etc,have been calculated by using the chemical bond theory of complex crystals of dielectric description.The results showed that in the crystals tbere are 16 kinds of bond which may be classified approximately in six types,namely:RP-O,O-H,S-O,C-O,C-C,and C-H.On the basis of the bondparameters of these bonds the refractive indexes of the crystals vvere thus calculated,the results were in good agreement vvith the experimentals.
- rare earth ethylsulphate,
- chemical bond,
- refractive index,
- polariziability
1. [1]
  Rui Li , Jiayu Zhang , Anyang Li . Two Levels of Understanding of Chemical Bonds: a Case of the Bonding Model of Hypervalent Molecules. University Chemistry, 2024, 39(2): 392-398. doi: 10.3866/PKU.DXHX202308051
2. [2]
  Qiwen Chen , Baolei Wang . Research Progress on One-Electron σ-Bond of Organic Compounds. University Chemistry, 2025, 40(11): 191-198. doi: 10.12461/PKU.DXHX202412136
3. [3]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
4. [4]
  Hequn Yang , Fei Rao , Dean Pan , Liu Chen , Numan Abbas , Gangqiang Zhu . Rare earth praseodymium single atoms on g-C₃N₄ tubes for enhanced in-plane charge transfer towards H₂O₂ production in pure water. Acta Physico-Chimica Sinica, 2026, 42(6): 100210-0. doi: 10.1016/j.actphy.2025.100210
5. [5]
  Xinghai Li , Zhisen Wu , Lijing Zhang , Shengyang Tao . Machine Learning Enables the Prediction of Amide Bond Synthesis Based on Small Datasets. Acta Physico-Chimica Sinica, 2025, 41(2): 100010-0. doi: 10.3866/PKU.WHXB202309041
6. [6]
  Wan Li , Xiaohang Qiu , Xiuyun Wang , Mei Shi , Xiuqiong Zeng , Yanping Ren , Faqiong Zhao , Min Hu , Yiru Wang , Juanjuan Song , Yongxian Fan , Dongcheng Liu , Wenwei Zhang , Weihong Li , Yong Fan , Jianrong Zhang , Shuyong Zhang . Specifications of Laboratory Water and Suggestions on the Use of Conductivity Meter. University Chemistry, 2026, 41(3): 77-86. doi: 10.12461/PKU.DXHX202507036
7. [7]
  Fangyan Zhang , Yuhan Li , Bowen He , Meng Lin , Ying Ma . Determination of Sodium Carbonate Content: A Conductometric Titration Approach. University Chemistry, 2026, 41(3): 373-380. doi: 10.12461/PKU.DXHX202505023
8. [8]
  Yan Long , Wenbo Zhao , Qing Cao , Xiangyu Li , Fukui Li , Yanwei Hu , Shiyu Song , Kaikai Liu . Phosphorescent carbon nanodot inks for scalable and high-resolution invisible printing. Acta Physico-Chimica Sinica, 2026, 42(3): 100198-0. doi: 10.1016/j.actphy.2025.100198
9. [9]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
10. [10]
  Xinxin YU , Yongxing LIU , Xiaohong YI , Miao CHANG , Fei WANG , Peng WANG , Chongchen WANG . Photocatalytic peroxydisulfate activation for degrading organic pollutants over the zero-valent iron recovered from subway tunnels. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 864-876. doi: 10.11862/CJIC.20240438
11. [11]
  Yongxin LIU , Xingchen LI , Hongjia LIU , Danni LI , Tao ZHANG , Xi CHEN . Enhancement effect of Fe₃O₄ conversion to MIL-100(Fe) on activation of persulfate for degradation of antibiotic. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2503-2513. doi: 10.11862/CJIC.20250169
12. [12]
  Chunfang Zhang , Cuimiao Zhang , Shuai Liu , Yaduo Zheng , Lin Yang , Kehan Jiang , Mingtao Run . Refined Experiment for Magnetic Susceptibility Determination: A Digital Empowered Experiment Based on WeChat Mini Program and Animated Video. University Chemistry, 2026, 41(1): 244-252. doi: 10.12461/PKU.DXHX202505056
13. [13]
  Anqi LI , Wenjing YANG , Xueming LI , Yanfong REN . Performance and mechanism of a foam Ti/FeCo-Fe₂O₃-CoFe₂O₄/SnO₂-Sb anode for synergistic activation of peroxymonosulfate toward degradation of organic pollutants. Chinese Journal of Inorganic Chemistry, 2026, 42(5): 944-958. doi: 10.11862/CJIC.20250323
14. [14]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
15. [15]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
16. [16]
  Jiantuo Chen , Fanpeng Shang , Mingxin Zheng . Analysis and Expansion of Metal-Metal Multiple Bond Related Questions in the 38th Chemistry Olympiad (Preliminary). University Chemistry, 2026, 41(2): 435-438. doi: 10.12461/PKU.DXHX202502043
17. [17]
  Yun Chen , Daijie Deng , Li Xu , Xingwang Zhu , Henan Li , Chengming Sun . Covalent bond modulation of charge transfer for sensitive heavy metal ion analysis in a self-powered electrochemical sensing platform. Acta Physico-Chimica Sinica, 2026, 42(1): 100144-0. doi: 10.1016/j.actphy.2025.100144
18. [18]
  Yafei Wang , Yan Zhang , Wei Li , Tingting Wang , Jiexuan Yang , Hui He , Ying Guan , Yongjun Zhang . The Secret Dance of Colors: Exploring How Colloidal Crystals Refract Beautiful Light and Shadows. University Chemistry, 2026, 41(4): 417-423. doi: 10.12461/PKU.DXHX202504026
19. [19]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
20. [20]
  Xie Yao , Li Shuangjun , Chen Chao , Fan Siyu , Tao Ying , Zhang Qitao . Ionic polarization engineering of polymeric carbon nitride toward efficient H₂O₂ photosynthesis. Acta Physico-Chimica Sinica, 2026, 42(5): 100183-. doi: 10.1016/j.actphy.2025.100183

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1051)
HTML views(189)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return