Home

Citation: Wang Wei, Li Laiming, Xi Shiquan. Studies on Phase Transition Behavior of Anhydrous Phospholipid by lnfrared and Raman Spectroscopy[J]. Chinese Journal of Applied Chemistry, ;1994, 11(1): 92-95. shu

Studies on Phase Transition Behavior of Anhydrous Phospholipid by lnfrared and Raman Spectroscopy

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 27 March 1993
Available Online: 27 September 1993

The temperature dependence of the infrared and Raman spectra of anhydrous dimyristoylphosphatidylethanolamine(DMPE) was investigated in the temperature rangefrom 290 to 405K. The spectra of the C-H,C=O and PO₂^- stretching mode regions reflectthat a cooperative phase transition occurs at about 365K. During the transition a significantlateral expansion of the lipid bilayer is present and accompanied both by an increased number of gauche rotamers within the hydrocarbon chain region and by muItiple conformers in boththe head group and glycerol backbone moieties. When the lipids are rapidly cooled,the acylchain region reorders without a concomitant reordering of the head group and interface region.
- dimyristoylphsphatidylethanolamine,
- molecular conformation,
- infrared spec-troscopy,
- Raman spectroscopy
1. [1]
  Zhengxuan Chang , Haoyang Jiang , Weiguang Zhao . Development of an AI-powered infrared spectroscopy recognition and teaching assistance system for halogenated n-butane preparation experiment. University Chemistry, 2026, 41(7): 430-440. doi: 10.12461/PKU.DXHX202505070
2. [2]
  Tianlong Zhang , Rongling Zhang , Hongsheng Tang , Yan Li , Hua Li . Online Monitoring and Mechanistic Analysis of 3,5-diamino-1,2,4-triazole (DAT) Synthesis via Raman Spectroscopy: A Recommendation for a Comprehensive Instrumental Analysis Experiment. University Chemistry, 2024, 39(6): 303-311. doi: 10.3866/PKU.DXHX202312006
3. [3]
  Lihua Jin , Lei Tian , Chaozhan Wang , Jiawei Liu , Quan Bai , Yan Li . Teaching Exploration and Practice of the Instrumental Analysis Experiment “Distinguishing Green Plastic Bags by Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy”. University Chemistry, 2026, 41(2): 360-365. doi: 10.12461/PKU.DXHX202502089
4. [4]
  Jiajie Li , Xiaocong Ma , Jufang Zheng , Qiang Wan , Xiaoshun Zhou , Yahao Wang . Recent Advances in In-Situ Raman Spectroscopy for Investigating Electrocatalytic Organic Reaction Mechanisms. University Chemistry, 2025, 40(4): 261-276. doi: 10.12461/PKU.DXHX202406117
5. [5]
  Yan Li , Fei Ding , Jing Wang . Application of Self-Constructed Raman Spectrometer in Instrumental Analysis Experiment Teaching. University Chemistry, 2026, 41(3): 363-372. doi: 10.12461/PKU.DXHX202505047
6. [6]
  Kaifu Zhang , Shan Gao , Bin Yang . Application of Theoretical Calculation with Fun Practice in Raman Spectroscopy Experimental Teaching. University Chemistry, 2025, 40(3): 62-67. doi: 10.12461/PKU.DXHX202404045
7. [7]
  Supin Zhao , Jing Xie . Understanding the Vibrational Stark Effect of Water Molecules Using Quantum Chemistry Calculations. University Chemistry, 2025, 40(3): 178-185. doi: 10.12461/PKU.DXHX202406024
8. [8]
  Jing Wang , Xue Qi , Yan Li , Zhihui Wen , Zhanheng Feng , Xiaohang Qiu . 散射光中的隐秘指纹——拉曼光谱. University Chemistry, 2026, 41(4): 280-288. doi: 10.12461/PKU.DXHX202507031
9. [9]
  Yang Wang , Yunpeng Fu , Xiaoji Liu , Guotao Zhang , Guobin Li , Wanqiang Liu , Jinglun Wang . Structural Analysis of Nitrile Solutions Based on Infrared Spectroscopy Probes. University Chemistry, 2025, 40(4): 367-374. doi: 10.12461/PKU.DXHX202406113
10. [10]
  Yufan ZHAO , Jinglin YOU , Shixiang WANG , Guopeng LIU , Xiang XIA , Yingfang XIE , Meiqin SHENG , Feiyan XU , Kai TANG , Liming LU . Raman spectroscopic quantitative study of the melt microstructure in binary Li₂O-GeO₂ functional crystals. Chinese Journal of Inorganic Chemistry, 2025, 41(8): 1533-1544. doi: 10.11862/CJIC.20250063
11. [11]
  Yongchao ZHU , Wenjie LIANG , Hai XU . Raman spectroscopic layer-dependent of Bi₂SeO₅ nanosheets and their encapsulation performance for two-dimensional materials. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 584-592. doi: 10.11862/CJIC.20250217
12. [12]
  Zhuomin Zhang , Hanbing Huang , Liangqiu Lin , Jingsong Liu , Gongke Li . Course Construction of Instrumental Analysis Experiment: Surface-Enhanced Raman Spectroscopy for Rapid Detection of Edible Pigments. University Chemistry, 2024, 39(2): 133-139. doi: 10.3866/PKU.DXHX202308034
13. [13]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
14. [14]
  Wei Peng , Baoying Wen , Huamin Li , Yiru Wang , Jianfeng Li . Exploration and Practice on Raman Scattering Spectroscopy Experimental Teaching. University Chemistry, 2024, 39(8): 230-240. doi: 10.3866/PKU.DXHX202312062
15. [15]
  Zhaoyue Lü , Zhehao Chen , Yi Ni , Duanbin Luo , Xianfeng Hong . Multi-Level Teaching Design and Practice Exploration of Raman Spectroscopy Experiment. University Chemistry, 2024, 39(11): 304-312. doi: 10.12461/PKU.DXHX202402047
16. [16]
  Liang MA , Honghua ZHANG , Weilu ZHENG , Aoqi YOU , Zhiyong OUYANG , Junjiang CAO . Construction of highly ordered ZIF-8/Au nanocomposite structure arrays and application of surface-enhanced Raman spectroscopy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1743-1754. doi: 10.11862/CJIC.20240075
17. [17]
  Jing Wang , Runlin Xia , Yuxuan Zhou , Yuping Liu . Research on electrochemical in situ Raman spectroscopy for nitrate reduction to ammonia: a recommended advanced instrument analysis innovative experiment. University Chemistry, 2026, 41(6): 221-229. doi: 10.12461/PKU.DXHX202506079
18. [18]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
19. [19]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
20. [20]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(725)
HTML views(75)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return