Citation:
Wang Daoquan, Chen Jinghong. Synthesis of 1,13-(Substituted methylene)-α-hydroxymethylcyclododecanol and Conformational Analysis of Possible Stereoisomers[J]. Chinese Journal of Applied Chemistry,
;1996, 13(3): 25-29.
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Nine title compounds were synthesized from α-ethoxycarbonylcyclododecanone by reduction and condensation with aldehydes or ketones.Their structure was confirmed by IR, MS,1 NMR and elemental analysis.Conformational analysis of possible stereoisomers was carried out and the result was supported by 1 NMR.The pesticidal activities were examined and some of them found to be effective in promoting the growth of plant.
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