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Citation: Xu Pianpian, Zhang Fanxian, Wang Wenfeng, Pen Yiru. Oxidative Carbonylation of Aniline by Pd/C Catalyst[J]. Chinese Journal of Applied Chemistry, ;1997, 14(4): 41-45. shu

Oxidative Carbonylation of Aniline by Pd/C Catalyst

1.
1. Department of Chemistry, State Key Laboratory of Physical Chemistry of Solid Surface, Institute of Physical Chemistry, Xiamen University, Xiamen 361005;
2.
2. Department of Chemistry, Fuzhou University, Fuzhou;
3.
3. Department of Chem istry, Fujian Normal University, Fuzhou

Received Date: 31 December 1996
Available Online: 5 May 1997

The effects of the preparation conditions of Pd/C catalyst and the promoters on the catalytic property have been investigated. The influences of partial oxygen pressure and addition of nitrobenzene on the oxidative carbonylation of aniline to ethyl N-phenyl carbamate also have been tested. The Pd/C catalyst was characterized by XPS, TPR and in-situ IR techniques. A possible mechanism of the oxidative carbonylation of aniline catalyzed by Pd/C-NaI system in alcohol medium has been proposed.
- aniline,
- oxidative carbonylation,
- ethyl N-phenyl carbamate,
- palladium
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