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Citation: Zhang Wanxuan, Lei Cenan, Huang Jinxia, Chen Jiawei. Synthesis of 1-Cyano-2,3,5-tri-O-benzoyl-β-D-ribofuranose[J]. Chinese Journal of Applied Chemistry, ;1997, 14(3): 115-116. shu

Synthesis of 1-Cyano-2,3,5-tri-O-benzoyl-β-D-ribofuranose

1.
Department of Chemistry, Hubei University, Wuhan 430062

Received Date: 12 August 1996
Available Online: 5 March 1997

Reacting guanosine with benzoyl chloride gave a mixture containing 2',3',5'-tribenzoyl guanosine. After distillation in vacuum the residual solid was acetylated directly and 1-O-acetyl-2,3,5-tri-O-benzoyl-U-D-ribofuranose (2) was obtained. Being reacted with Me₃SiCN, (2) led to the title compound(1). The method reported here is more convenient and cheaper with a considerably higher yield.
- guanosine,
- cyano-tri-O-benzoyl-U-D-ribofuranose,
- synthesis,
- chloro-trimethylsilane
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