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Citation: Wang Wei, Guo Hetong, Gao Jianping, Qin Qixian. Effect of ZrO₂ Particles on the Crystal Structure of Matrix Ni in Ni ZrO₂ Composite Plating[J]. Chinese Journal of Applied Chemistry, ;1997, 14(1): 6-10. shu

Effect of ZrO₂ Particles on the Crystal Structure of Matrix Ni in Ni ZrO₂ Composite Plating

1.
Department of Applied Chemistry, Tianjin University, Tianjin 300072

Received Date: 21 May 1996
Available Online: 22 October 1996
Fund Project:

Ni-ZrO₂ composite plating was prepared by composite electrodeposition method, and the change of crystal preferential orientation and lattice parameter of matrix metal Ni caused by ZrO₂ particles and its effect on the hydrogen evolution activity were investigated from the view of interaction between matrix metal and particles. The presence of ZrO₂ particles has significant effect on the crystal structure of electrodeposited matrix metal Ni, and leads to a new crystal preferential orientation along (220) crystal face. This new crystal preferential orientation is unfavorable to the hydrogen evolution reaction. These results show that in the course of electrodeposition, Ni and ZrO₂ particles enter into composite plating in a definite interfacial coupling relation, which is also proved by the data of the change in the lattice parameter of matrix metal Ni.
- Ni-ZrO₂ composite plating,
- interface,
- preferential orientation,
- hydrogen evolution
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Effect of ZrO₂ Particles on the Crystal Structure of Matrix Ni in Ni ZrO₂ Composite Plating