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Citation: Yu Bin, Ding Mengxian, Wang Fosong. ASYMMETRIC POLYMERIZATION OF TRIPHENYLMETHYL ACRYLATE AND DIPHENYL-o-TOLYLMETHYL ACRYLATE[J]. Chinese Journal of Applied Chemistry, ;1993, 10(6): 89-91. shu

ASYMMETRIC POLYMERIZATION OF TRIPHENYLMETHYL ACRYLATE AND DIPHENYL-o-TOLYLMETHYL ACRYLATE

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun

Received Date: 2 March 1993
Available Online: 22 June 1993
Fund Project:

Triphenylmethyl acrylate and diphenyl-o-tolylmethyl acrylate were synthesized for the first time. Optically active polymers with one-handed helical conformations can be obtained through asymmetric polymerization of the above two monomers in the presence of chiral ligands. Compared with poly(triphenylmethyl methacrylate), both poly(triphenylmethyl acrylate) and poly(diphenyl-o-tolylmethyl acrylate) showed lower specific rotations due to the absence of methyl group at the a position of the double bonds.
- triphenylmethyl acrylate,
- diphenyl-o-tolylmethyl acrylate,
- asymmetric polymerization,
- one-handed helical conformation
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