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Fang Tianru, Xu Zhengyan, Xu Suxian. WATER-SOLUBLE AND AMPHIPHILIC POLYMERS 16. SYNTHESIS AND CHARACTERIZATION OF POLYSTYRENE/POLYACRYLAMIDE BLOCK POLYMERS[J]. Chinese Journal of Applied Chemistry,
;1993, 10(1): 16-20.
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A polyazoester initiator was used to synthesize polystyrene/polyaerylamide (PSt/PAM) block polymers by its consecutive decomposition in styrene(St) and aerylamide(AM). The polymerization behavior of AM in 1,4-dioxane initiated by an azo group-containing styrene prepolymer (prePSt) was investigated, and the factors influencing the conversion of the second monomer and the content of the homopolystyrene were discussed. The PSt/PAM block polymers were characterized by elemental analysis, solubility, IR, DSC, TGand pyrolysis-gas chromatography.
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