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Citation: YANG Jin-Tian, CHENG Hai-Xing, HUANG Wei. Synthesis and Characterization of 2,5-Di-tert-butyl-1,4-di-(p-benzoic acid oxyl) benzene[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 1489-1491. shu

Synthesis and Characterization of 2,5-Di-tert-butyl-1,4-di-(p-benzoic acid oxyl) benzene

1.
a Department of Chemistry, Huzhou Teachers College, Huzhou 313000;
2.
b College of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai

Corresponding author: YANG Jin-Tian,
Received Date: 10 December 2008
Available Online: 5 March 2009
Fund Project: 浙江省自然科学基金(Y4080421)资助项目 (Y4080421)

2,5-Di-tert-butyl 1,4-di-(p-phenylene nitriles oxyl) benzene was synthesized via nucleophilic substitution reaction of 4-fluorobenzonitrile with 2,5-di-tert-butyl-p-dihydroxybenzene(yield 87.00%,white crystals,mp 280 ℃).Then 2,5-di-tert-butyl-1,4-di-(p-benzoic acid oxyl) benzene with two ether bonds and two tert-butyls was obtained by alkaline hydrolysis of 2,5-di-tert-butyl 1,4-di-(p-phenylene nitriles oxyl) benzene(yield 72.78%,white acicular crystals,mp>340 ℃).The chemical structure of this product was confirmed by means of elemental analysis,IR,¹H NMR,¹³C NMR and MS.
- di-tert-butyl-di-(p-benzoic acid oxyl) benzene,
- synthesis,
- characterization
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