Home

Citation: ZHANG You-Ming, WANG Ai-Xia, LENG Yan-Li, WANG Ya-Lin, WEI Tai-Bao. 1,3-Benzyldiacyl Hydrazone Tweezers Receptors:Synthesis and Anions Recognition Properties[J]. Chinese Journal of Applied Chemistry, ;2009, 26(11): 1253-1258. shu

1,3-Benzyldiacyl Hydrazone Tweezers Receptors:Synthesis and Anions Recognition Properties

1.
College of Chemistry and Chemical Engineering, Gansu Key Laboratory of Polymer Materials, Northwest Normal University, Lanzhou 730070

Corresponding author: WEI Tai-Bao,
Received Date: 29 August 2008
Available Online: 2 June 2009
Fund Project: 国家自然科学基金(20671077) (20671077)甘肃省自然科学基金(3ZS061-A25-027,2008-1-164)资助项目 (3ZS061-A25-027,2008-1-164)

Three novel 1,3-benzyldiacyl hydrazone derivatives(4a～4c) were designed and synthesized.The binding properties of the receptor with anions such as F^-,Cl^-,Br^-,I-,CH₃COO^-,HSO₄^-,H₂PO₄^- and ClO₄^- in DMSO were investigated by UV-Vis and ¹H NMR.As a result,receptor 4a(1,3-benzyldi(4-nitropheyl-2-furfuraldehyde) methacylhydrazone) can recognize anions through hydrogen bonding in DMSO solutions.A clear color change was observed from yellow to dark yellow and pale red upon addition of F-and CH₃COO^-.¹H NMR titration and solvation effect confirm hydrogen bonding interaction between the receptor and the anions.Job curve indicates that a 1:1 stoichiometry complex is formed between the receptor and the two kinds of anions.Based on the above results,the recognition binding mode was discussed.The molecular recognition ability was discussed in terms of the size and shape-fit as well as the recognition model between host and guest molecules.
- molecular tweezer,
- anion recognition,
- UV-Vis absorption spectrum,
- benzyldiacyl hydrazone
1. [1]
  Yi Li , Zhaoxiang Cao , Peng Liu , Xia Wu , Dongju Zhang . Revealing the Coloration and Color Change Mechanisms of the Eriochrome Black T Indicator through Computational Chemistry and UV-Visible Absorption Spectroscopy. University Chemistry, 2025, 40(3): 132-139. doi: 10.12461/PKU.DXHX202405154
2. [2]
  Yanan Fan , Jingjing Huang . Interactive Electronic Courseware Facilitates the Development of Integrated Undergraduate-Graduate Instrumental Analysis Laboratory Courses: A Case Study of UV-Vis Spectroscopy Analysis Experiment. University Chemistry, 2025, 40(10): 282-287. doi: 10.12461/PKU.DXHX202411009
3. [3]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
4. [4]
  Xiaomei Ai , Muran Lin , Jinlan Zeng , Jiwei Ren . 可见光催化绿色合成二肽化合物. University Chemistry, 2026, 41(5): 358-367. doi: 10.12461/PKU.DXHX202510007
5. [5]
  Fengying Zhang , Yanglin Mei , Yuman Jiang , Shenshen Zheng , Kaibo Zheng , Ying Zhou . Research progress of transient absorption spectroscopy in solar energy conversion and utilization. Acta Physico-Chimica Sinica, 2025, 41(9): 100118-0. doi: 10.1016/j.actphy.2025.100118
6. [6]
  Peiru Fan , Lichun Zhang , Hongjie Song , Yi Lv , Rui Liu . Exploring Atomic Absorption Spectroscopy: From Phenomenon to Technological Innovation. University Chemistry, 2026, 41(2): 344-352. doi: 10.12461/PKU.DXHX202503038
7. [7]
  Cailin Song , Wenqi Liu , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Iron/Zinc/Copper/Manganese in Aloe vera and Ganoderma lucidum Using Flame Atomic Absorption Spectrometry. University Chemistry, 2026, 41(4): 356-362. doi: 10.12461/PKU.DXHX202505098
8. [8]
  Dan Liu . 可见光-有机小分子协同催化的不对称自由基反应研究进展. University Chemistry, 2025, 40(6): 118-128. doi: 10.12461/PKU.DXHX202408101
9. [9]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-0. doi: 10.3866/PKU.WHXB202406014
10. [10]
  Mengyao Shi , Kangle Su , Qingming Lu , Bin Zhang , Xiaowen Xu . Determination of Potassium Content in Tobacco Stem Ash by Flame Atomic Absorption Spectroscopy. University Chemistry, 2024, 39(10): 255-260. doi: 10.12461/PKU.DXHX202404105
11. [11]
  Lingling Li , Zhe Chen . Charge transfer mechanism investigation of S-scheme photocatalyst using soft X-ray absorption spectroscopy. Acta Physico-Chimica Sinica, 2026, 42(4): 100215-0. doi: 10.1016/j.actphy.2025.100215
12. [12]
  Bing LIU , Huang ZHANG , Hongliang HAN , Changwen HU , Yinglei ZHANG . Visible light degradation of methylene blue from water by triangle Au@TiO₂ mesoporous catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 941-952. doi: 10.11862/CJIC.20230398
13. [13]
  Senqiang Zhu , Ruohan Li , Yujia Yang , Jinzhi Liao , Rui Liu . 聚光成辉——Suzuki偶联反应高效制备聚集诱导发射荧光分子及其潜指纹识别应用. University Chemistry, 2026, 41(5): 109-119. doi: 10.12461/PKU.DXHX202511066
14. [14]
  Mengfan Gong , Dongju Zhang . Estimating Delocalization Energies of 1,3-Butadiene and Benzene with Isodesmic Reactions: A Relatively Precise Approach. University Chemistry, 2026, 41(4): 457-463. doi: 10.12461/PKU.DXHX202505036
15. [15]
  Zilin Hu , Yaoshen Niu , Xiaohui Rong , Yongsheng Hu . Suppression of Voltage Decay through Ni³⁺ Barrier in Anionic-Redox Active Cathode for Na-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306005-0. doi: 10.3866/PKU.WHXB202306005
16. [16]
  Junyang FENG , Xiaoli HAN , Yongjie SONG , Gang LI . Proton conduction and fluorescence properties of an ionic hydrogen-bonded organic framework constructed from dibromophthalic acid. Chinese Journal of Inorganic Chemistry, 2026, 42(4): 693-702. doi: 10.11862/CJIC.20250350
17. [17]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
18. [18]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . Accelerated Interfacial Electron Transfer in Perovskite Solar Cell by Ammonium Hexachlorostannate Modification and fs-TAS Investigation. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-0. doi: 10.3866/PKU.WHXB202402006
19. [19]
  Yiting Huo , Xin Zhou , Feifan Zhao , Chenbin Ai , Zhen Wu , Zhidong Chang , Bicheng Zhu . Boosting photocatalytic CO₂ methanation through TiO₂/CdS S-scheme heterojunction and fs-TAS mechanism study. Acta Physico-Chimica Sinica, 2025, 41(11): 100148-0. doi: 10.1016/j.actphy.2025.100148
20. [20]
  Xin Zhou , Yiting Huo , Songyu Yang , Bowen He , Xiaojing Wang , Zhen Wu , Jianjun Zhang . Understanding the effect of pH on protonated COF during photocatalytic H₂O₂ production by femtosecond transient absorption spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(12): 100160-0. doi: 10.1016/j.actphy.2025.100160

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(908)
HTML views(104)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return