Home

Citation: TAO Jian-Qing, GU Yun-Lan, GU Zhi-Guo, ZUO Jing-Lin, YOU Xiao-Zeng. Synthesis and Magnetic Properties of Room-Temperature Spin Crossover Complex[Fe(dpp)(Mepy)₂(NCS)₂][J]. Chinese Journal of Applied Chemistry, ;2009, 26(7): 791-794. shu

Synthesis and Magnetic Properties of Room-Temperature Spin Crossover Complex[Fe(dpp)(Mepy)₂(NCS)₂]

1.
a Jiangsu Provincial Key Laboratory of Coastal Wetland Bioresources and Environmental Protection, School Chemistry and Chemical Engineering Yancheng Teachers University, Yancheng 224002;
2.
b Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Corresponding author: TAO Jian-Qing,
Received Date: 30 June 2008
Available Online: 23 September 2008
Fund Project: 国家自然科学基金(20531040) (20531040)江苏省高校自然科学基础研究基金(08KJD150021) (08KJD150021)江苏省滩涂生物资源与环境保护重点建设实验室基金(JLCBE07010)资助项目 (JLCBE07010)

A new room-temperature spin crossover complex [Fe(dpp) (Mepy) ₂(NCS) ₂] was prepared.Elemental analysis,infrared spectroscopy,electrospray ionization mass spectrometry and ultraviolet spectro-scopy were used to study the structure of the complex.The temperature dependence of magnetic susceptibility shows that the temperature of spin transition is 330 K.By comparing the complex with the other resemblant structural complexes,it shows that the modification of ligand ha a great influence on the critical temperature and hysteresis loop of spin crossover.
- magnetic susceptibility,
- spin crossover,
- spin transition,
- molecul material
1. [1]
  Gengyuan Li , Yexin Wang , Song Gao , Shangda Jiang . Advances in Light-Induced Spin Polarization of Magnetic Molecules. University Chemistry, 2025, 40(12): 87-94. doi: 10.12461/PKU.DXHX202509112
2. [2]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
3. [3]
  Chunfang Zhang , Cuimiao Zhang , Shuai Liu , Yaduo Zheng , Lin Yang , Kehan Jiang , Mingtao Run . Refined Experiment for Magnetic Susceptibility Determination: A Digital Empowered Experiment Based on WeChat Mini Program and Animated Video. University Chemistry, 2026, 41(1): 244-252. doi: 10.12461/PKU.DXHX202505056
4. [4]
  Yinglian LI , Chengcheng ZHANG , Xinyu ZHANG , Xinyi WANG . Spin crossover in [Co(pytpy)₂]²⁺ complexes modified by organosulfonate anions. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1162-1172. doi: 10.11862/CJIC.20240087
5. [5]
  Yadan SUN , Xinfeng LI , Qiang LIU , Oshio Hiroki , Yinshan MENG . Structures and magnetism of dinuclear Co complexes based on imine derivatives. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2212-2220. doi: 10.11862/CJIC.20240131
6. [6]
  Wei Ren , Jinhe Li , Chengzhang Zhu , Weikang Wang , Qinqin Liu . Tailored spin states: a transformative paradigm for sustainable catalysis. Acta Physico-Chimica Sinica, 2026, 42(4): 100178-0. doi: 10.1016/j.actphy.2025.100178
7. [7]
  Jinwang Wu , Qijing Xie , Chengliang Zhang , Haifeng Shi . Rationally Designed ZnFe_1.2Co_0.8O₄/BiVO₄ S-Scheme Heterojunction with Spin-Polarization for the Elimination of Antibiotic. Acta Physico-Chimica Sinica, 2025, 41(5): 100050-0. doi: 10.1016/j.actphy.2025.100050
8. [8]
  Yang YANG , Pengcheng LI , Zhan SHU , Nengrong TU , Zonghua WANG . Plasmon-enhanced upconversion luminescence and application of molecular detection. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 877-884. doi: 10.11862/CJIC.20230440
9. [9]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . Hierarchical MoS₂/Ti₃C₂T_x heterostructure with excellent photothermal conversion performance for solar-driven vapor generation. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-0. doi: 10.1016/j.actphy.2025.100053
10. [10]
  Zhifang SU , Zongjie GUAN , Yu FANG . Process of electrocatalytic synthesis of small molecule substances by porous framework materials. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2373-2395. doi: 10.11862/CJIC.20240290
11. [11]
  Rui Xu , Wei Li , Tianyi Li . Exploration of Teaching Reform in the Course of “Principles of Chemical Engineering” in the Polymer Materials and Engineering Major. University Chemistry, 2025, 40(4): 54-58. doi: 10.12461/PKU.DXHX202404081
12. [12]
  Weijie Yang , Mansheng Chen , Chen Xu , Fujian Xu . Hydroxyl-Rich Polycations: Innovative Materials Empowering Life and Health. University Chemistry, 2025, 40(9): 332-343. doi: 10.12461/PKU.DXHX202410072
13. [13]
  Zhe Ji , Guangxu Lan , Jiangnan Li , Sihai Yang . A New Protocol to Construct Molecular Materials: A Brief Introduction on the 2025 Nobel Prize in Chemistry. University Chemistry, 2025, 40(12): 70-77. doi: 10.12461/PKU.DXHX202511097
14. [14]
  Lu Zheng , Yueying Sun , Xin Ding , Jitao Liu . Preparation of 3D Printed Metamaterials Based on Molecular Design. University Chemistry, 2026, 41(1): 253-263. doi: 10.12461/PKU.DXHX202506019
15. [15]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
16. [16]
  Jiamin Zhang , Zhen Fan , Jianzhong Du . Integrated Teaching Method Combining Domestic and International Perspectives: A Case Study on Cultivating Innovative Talents in Polymeric Biomaterials. University Chemistry, 2025, 40(7): 156-160. doi: 10.12461/PKU.DXHX202409131
17. [17]
  Chenfei Li , Xu Han , Qimeng Zhang , Ben Zhang , Xinyao Huang , Mingxiao Deng , Caixia Zheng , Haizhu Sun . Measurement of Stress-Strain Curves of Polymeric Materials Using a Non-Contact Displacement Detector. University Chemistry, 2026, 41(1): 179-187. doi: 10.12461/PKU.DXHX202505101
18. [18]
  Heng Zhang , Ying Ma , Shiling Yuan . Machine Learning-based Prediction of Antifouling Performance in Polymer Materials: An Integrated Molecular Simulation Experiment. University Chemistry, 2026, 41(1): 346-353. doi: 10.12461/PKU.DXHX202506015
19. [19]
  Bei Liu , Heng Li , Mei Yang , Yijiang Liu . Teaching Reform and Exploration in Polymer Chemistry with an “Experiment-Intensified” Approach for Masters in Materials and Chemical Engineering. University Chemistry, 2025, 40(4): 10-14. doi: 10.3866/PKU.DXHX202401010
20. [20]
  Yan Wang , Haolong Li , Chengji Zhao , Zheng Chen , Quan Lin , Yupeng Guo , Jianxin Mu , Kun Liu , Zhong-Yuan Lu , Junqi Sun . Construction Practice of the National First-Class Undergraduate Major in Polymer Materials and Engineering at Jilin University. University Chemistry, 2025, 40(4): 46-53. doi: 10.12461/PKU.DXHX202403083

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(558)
HTML views(29)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return

Synthesis and Magnetic Properties of Room-Temperature Spin Crossover Complex[Fe(dpp)(Mepy)2(NCS)2]

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Magnetic Properties of Room-Temperature Spin Crossover Complex[Fe(dpp)(Mepy)₂(NCS)₂]