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Citation: YUAN He-Fang, SUN Shu-Quan, SONG Qi-Jun, ZHENG Chang-Ge, DING Yu-Qiang. Synthesis and Electrochemiluminescence of Novel Ruthenium Complex [Rubis(bipyridyl)(3,4,7,8-tetrachrolo-1,10-phenanthroline)](PF₆)₂[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 726-729. shu

Synthesis and Electrochemiluminescence of Novel Ruthenium Complex [Rubis(bipyridyl)(3,4,7,8-tetrachrolo-1,10-phenanthroline)](PF₆)₂

1.
School of Chemical and Materials Engineering, Jiangnan University, Wuxi 214122

Corresponding author: SONG Qi-Jun,
Received Date: 11 May 2008
Available Online: 20 September 2008
Fund Project: 国家自然科学基金(20571033)资助项目 (20571033)

An o-phenanthroline-substituted ruthenium complex,[Rubis(bipyridyl)(3,4,7,8-tetrachrolo-1,10-phenanthroline)](PF₆)₂,was synthesized and the structure of the complex was characterized by elemental analysis,IR spectroscopy and ¹H NMR spectroscopy.The complex displayed absorption in the UV and visible regions,with a visible maximum absorption at 440 nm,a typical metal-to-ligand charge transfer(MLCT) transition.Photoluminescence emission also had the characteristics of MLCT transitions with the maxima wavelengths ranged from 630 to 649 nm depending on the solvent.The electrochemiluminescence(ECL) of the complex was found to be less dependant on pH,which was distinctly different from that of the well known ruthenium tris(bipyridine) complex.Furthermore the background ECL signal of the complex did not increase even under a strong alkaline condition.
- ruthenium tris(bipyridine) complex,
- electrochemiluminescence,
- tetrachrolo-o-phenanthroline,
- pH effect
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Synthesis and Electrochemiluminescence of Novel Ruthenium Complex [Rubis(bipyridyl)(3,4,7,8-tetrachrolo-1,10-phenanthroline)](PF6)2

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemiluminescence of Novel Ruthenium Complex [Rubis(bipyridyl)(3,4,7,8-tetrachrolo-1,10-phenanthroline)](PF₆)₂