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Citation: DENG Sheng-Jun, ZHANG Ning, CHEN Chao, XIAO Wei-Ming, HU Meng, YUAN Qiong. Solvothermal Synthesis,Structures and Spectroscopic Properties of Two Chalcanthite Derivatives[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 686-691. shu

Solvothermal Synthesis,Structures and Spectroscopic Properties of Two Chalcanthite Derivatives

1.
Department of Chemistry, Nanchang University, Nanchang 330031

Corresponding author: ZHANG Ning,
Received Date: 12 May 2008
Available Online: 21 July 2008
Fund Project: 国家自然科学基金(20701018)资助项目,江西省自然科学基金(2007GZH2755)资助项目,吉林大学无机合成与制备化学国家重点实验室开放课题(2006-003) (20701018)资助项目,江西省自然科学基金(2007GZH2755)资助项目,吉林大学无机合成与制备化学国家重点实验室开放课题(2006-003)

Two compounds,[Cu(im)₄SO₄]_n(1) and [Cu(bpy)(H₂O)₂SO₄]_n(2)(im=imidazole,bpy=2,2'-bipyridine),were synthesized in ethanol/DMF systems with HNO₃ in 67% and 82% yields,respectively.The relation between the crystal structure and acidity of the reaction system were investigated.As 0.35~0.6 mmol or 1.2~1.45 mmol HNO3 was added to the reaction system pure compound 1 or 2,respectively,was obtained.And they were further characterized by elemental analysis,IR,UV-Vis reflection spectra,inductively coupled plasma(ICP),TGA,X-ray powder diffraction and X-ray crystallography diffraction.The crystal structure analyses revealed that they all belong to the monoclinic system with space group C2/C,possessing chalcanthite-like configuration.Compound 1 exhibits a 1D zigzag chain structure,while 2 exhibits 1D linear chain,which is resulted from different ligands.UV-Vis reflection spectra of the two compounds indicated that the absorption bands in visible region are from the d-d transitions of copper(Ⅱ) ions and the absorption bands in ultraviolet region correspond to ligand→copper(Ⅱ) charge transfer and π→π* transition for compounds 1 and 2,respectively.
- chalcanthite,
- copper sulfate,
- solvothermal synthesis,
- UV-Vis spectroscopy
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