Home

Citation: LI Xiao-Xia, XU Ai-Hua, XIE Wei-Yang, MA Xiao-Jun. Oxidative Degradation of Alginate by Hydrogen Peroxide[J]. Chinese Journal of Applied Chemistry, ;2009, 26(6): 625-628. shu

Oxidative Degradation of Alginate by Hydrogen Peroxide

LI Xiao-Xia ^a,b ,
XU Ai-Hua ^a,b ,
XIE Wei-Yang ^a ,
MA Xiao-Jun ^a,,

1.
a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023;
2.
b Graduate School of the Chinese Academy of Sciences, Beijing

Corresponding author: MA Xiao-Jun,
Received Date: 10 June 2008
Available Online: 1 September 2008
Fund Project: 国家科技部“九七三”项目(2007CB714305) (2007CB714305)国家自然科学基金重点资助项目(20736006) (20736006)

The clean and effective oxidant,hydrogen peroxide,was used to degrade alginate in order to prepare its low molecular products,and the effects of pH,temperature,amount of H₂O₂ and metal ions on the degradation were investigated.The degradation rate increased with the decrease of solution pH,and the increases of reaction temperature and oxidant dosage.Low molecular alginate could be obtained effectively with pH of 5.3,temperature of 50 ℃ and H₂O₂ of 0.5% for 2 h reaction.The reaction could be also significantly accelerated by 4 mg/L Cu²⁺ or Fe²⁺.GPC analysis showed that the average molecular mass of alginate was decreased and the molecular mass distribution was broadened.It can be inferred from FTIR that the degradation was caused by OH radicals produced by hydrogen peroxide,which resulted in the breakage of the glycosidic C(1)—O—C(4) bond.
- alginate,
- hydrogen peroxide,
- oxidation,
- degradation
1. [1]
  Peng YUE , Liyao SHI , Jinglei CUI , Huirong ZHANG , Yanxia GUO . Effects of Ce and Mn promoters on the selective oxidation of ammonia over V₂O₅/TiO₂ catalyst. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 293-307. doi: 10.11862/CJIC.20240210
2. [2]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
3. [3]
  Xiaoning TANG , Junnan LIU , Xingfu YANG , Jie LEI , Qiuyang LUO , Shu XIA , An XUE . Effect of sodium alginate-sodium carboxymethylcellulose gel layer on the stability of Zn anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1452-1460. doi: 10.11862/CJIC.20240191
4. [4]
  Haoyuan Qin , Lijing Wang , Yuanhao Tang , Weilong Shi , Changyu Lu . Modulating charge kinetics in CDs/CTF S-scheme hybrids for enhanced H₂O₂ photosynthesis. Chinese Journal of Structural Chemistry, 2026, 45(4): 100858-100858. doi: 10.1016/j.cjsc.2025.100858
5. [5]
  Junjie Wang , Shulin Gao , Sujuan Hu . Zinc-air battery-H₂O₂ generation system: Current progress, key challenges, optimization strategies and future developments. Chinese Chemical Letters, 2026, 37(6): 111000-. doi: 10.1016/j.cclet.2025.111000
6. [6]
  Yijie Zhong , Yurun Tong , Weitao Wang , Ru Qiao , Jing Zhang , Enlai Hu , Peijun Gong . 基于“双极”技术的电势-pH图解析与电化学性能优化基础实验. University Chemistry, 2026, 41(5): 264-274. doi: 10.12461/PKU.DXHX202511071
7. [7]
  Peiyu Zhang , Aixin Song , Jingcheng Hao , Jiwei Cui . 高频超声法制备聚多巴胺薄膜综合实验. University Chemistry, 2025, 40(6): 210-214. doi: 10.12461/PKU.DXHX202407081
8. [8]
  Qi Zhang , Ziyu Liu , Hongxia Tan , Jun Tong , Dazhen Xu . Research Progress on Direct Synthesis of β-Hydroxy Sulfones via Difunctionalization of Olefins. University Chemistry, 2025, 40(11): 199-209. doi: 10.12461/PKU.DXHX202412064
9. [9]
  Wei Zhang , Lei Yang , Zhihang Jin , Shusheng Zhang , Fawei Zhu , Zhanxian Li , Mingming Yu . Fluorescent probes reveal the differential impact of ferroptosis inhibition on drug-induced liver and kidney injury. Chinese Chemical Letters, 2026, 37(4): 111220-. doi: 10.1016/j.cclet.2025.111220
10. [10]
  Zhimin Yuan , Xingling Zhao , Xianglin Zhu , Kaili Wang , Ya-Qian Lan , Zaiyong Jiang . Solar-driven hydrogen peroxide production on designed g-C₃N₄: Strategies, mechanisms, and perspectives. Chinese Chemical Letters, 2026, 37(6): 112572-. doi: 10.1016/j.cclet.2026.112572
11. [11]
  Fei ZHOU , Xiaolin JIA . Co₃O₄/TiO₂ composite photocatalyst: Preparation and synergistic degradation performance of toluene. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2232-2240. doi: 10.11862/CJIC.20240236
12. [12]
  Ruru MA , Yingjie SONG , Yahui LI , Ermin ZHOU , Deqiang LI , Xiaojuan HUANG , Jun LI . Synergistic nitrogen doping and carbon support in TiO₂ for enhanced photocatalytic degradation of methylene blue and oxytetracycline. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 641-656. doi: 10.11862/CJIC.20250221
13. [13]
  Zhiqiang XING , Jinling LIU , Mingmin SU , Lei ZHANG , Lijun YANG . CoNi dual-single-atom catalyst for electrocatalytic H₂O₂ production and in situ electro-Fenton degradation of pollutants. Chinese Journal of Inorganic Chemistry, 2025, 41(12): 2479-2490. doi: 10.11862/CJIC.20250181
14. [14]
  Shumin Zhang , Yaqi Wang , Zelin Wang , Libo Wang , Changsheng An , Difa Xu . Ultrafast electron transfer at the ZIS_1−x/UCN S-scheme interface enables efficient H₂O₂ photosynthesis coupled with tetracycline degradation. Acta Physico-Chimica Sinica, 2025, 41(11): 100136-0. doi: 10.1016/j.actphy.2025.100136
15. [15]
  Ning CHEN , Jingle CHEN , Hongyuan ZHU , Huali CHEN , Liguang WU , Ting WANG . Mechanism and performance regulation of Co/Zr-doped mesoporous TiO₂ catalysts in activating sodium persulfate for tetracycline degradation. Chinese Journal of Inorganic Chemistry, 2026, 42(3): 507-518. doi: 10.11862/CJIC.20250275
16. [16]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
17. [17]
  Yaping ZHANG , Tongchen WU , Yun ZHENG , Bizhou LIN . Z-scheme heterojunction β-Bi₂O₃ pillared CoAl layered double hydroxide nanohybrid: Fabrication and photocatalytic degradation property. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 531-539. doi: 10.11862/CJIC.20240256
18. [18]
  Yuanqing Wang , Yusong Pan , Hongwu Zhu , Yanlei Xiang , Rong Han , Run Huang , Chao Du , Chengling Pan . Enhanced Catalytic Activity of Bi₂WO₆ for Organic Pollutants Degradation under the Synergism between Advanced Oxidative Processes and Visible Light Irradiation. Acta Physico-Chimica Sinica, 2024, 40(4): 2304050-0. doi: 10.3866/PKU.WHXB202304050
19. [19]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
20. [20]
  Cheng Qiang , Li Jingping , Ke Zhendong , Li Jiaming , Wang Kai . Advanced oxidation technology synergistic photothermal degradation of antibiotics over inorganic/organic S-scheme heterojunction. Acta Physico-Chimica Sinica, 2026, 42(5): 100187-. doi: 10.1016/j.actphy.2025.100187

Get Citation

PDF

XML

Metrics

PDF Downloads(1)
Abstract views(669)
HTML views(74)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return