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Citation: YAN Zhi-Jun, JIAO Bao-Juan, GAO Sheng-Li. Preparation of A New Energetic Complex CuATZ·2H₂O[J]. Chinese Journal of Applied Chemistry, ;2009, 26(4): 483-485. shu

Preparation of A New Energetic Complex CuATZ·2H₂O

1.
a Chemistry Department, Xi'an College of Arts and Science, Xi'an 710065;
2.
b Chemistry Department, Northwest University, Xi'an

Corresponding author: JIAO Bao-Juan,
Received Date: 21 April 2008
Available Online: 30 June 2008

A new energetic complex of copper(Ⅱ) was prepared and identified as CuATZ·2H₂O(ATZ2-=5,5'-azotetrazolate) by chemical analysis.The solubility of the complex was determined.The enthalpy change of the liquid-phase reaction for the formation of the complex,Δ_rH_m^θ(l),was determined to be(-39.182±0.097) kJ/mol at 298.15 K by microcalorimetry.On the basis of experimental and calculated results,the thermodynamic and kinetic parameters of the liquid-phase reaction for the formation of the complex were obtained at different temperatures.The lower apparent activation energy E(24.880 5 kJ/mol) benefited the proceeding of the reaction under ordinary experimental conditions.However the complex can not be used as a component in solid propellants due to its sensitivity to shock and impact at room temperature at mg quantity and increased risk of explosion upon friction and static charge at about 60 ℃.
- energetic complex,
- CuATZ·2H₂O,
- combustion catalyst,
- microcalorimetric method
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Preparation of A New Energetic Complex CuATZ·2H2O

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通讯作者: 陈斌, bchen63@163.com

Preparation of A New Energetic Complex CuATZ·2H₂O