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Citation: Chen Ke, Song Lulin. SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES[J]. Chinese Journal of Applied Chemistry, ;1990, 7(3): 24-28. shu

SYNTHESIS AND CHARACTERIZATION OF OXO-BRIDGED TRI-AND TETRANUCLEAR MANGANESE SALICYLIDENE-β-ALANINE COMPLEXES

Chen Ke ,
Song Lulin

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027

Received Date: 6 July 1989
Available Online: 23 October 1989

Oxo-bridged tri-and Tetranuclear manganese complexes:Mn₃O(salala-β)₃·3H₂O and Mn₄O₂ (salala-β)₃ (ClO₄)₂·8H₂O, where salala-β^2- is the dianion of tridentate Shiff base sali-cylidene-β-alanine, have been synthesized and characterized by elemental analyses,valence determination, electronic conductivity,magnetic susceptibility, thermogravimetric analyses,infrared and electronic spectra etc. The possible structures of the complexes are suggested.
- manganese,
- salicylidene-β-alanine,
- trinuclear complex,
- tetranuclear complex
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