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Citation: Guo Boshu, Zhou Jingyu, Yao Yuangen, You Xiaozeng. STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDITIVE REACTION FOR Ni[CF₃COCHC(C₄H₄S)=NCH₂]₂ WITH SOME FIVE-MEMBERED HETEROCYCLES BY GLC METHOD[J]. Chinese Journal of Applied Chemistry, ;1989, 6(4): 59-61. shu

STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDITIVE REACTION FOR Ni[CF₃COCHC(C₄H₄S)=NCH₂]₂ WITH SOME FIVE-MEMBERED HETEROCYCLES BY GLC METHOD

1.
Coordination Chemistry Institute, Nanjing University

Received Date: 19 July 1988
Available Online: 18 January 1989

The solubillty constants K°_R of some five-membered heterocycles i.e. furan, thiophene and pyrrole, the apparent equilibrium constants KR and the stability constants K₁ of these Lewis bases with Lewis acid Ni [CF₃COCHC(C₄H₄S)=NCH₂]₂ in squalane solution are determined by GLC method. The thermodynamic parameters are calculated with the relation -RlnK₁~1/T. The results of the experiments have been analysed.
- GLC,
- Aoid-base adduct reaction,
- Thermodynamic parameter
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STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDITIVE REACTION FOR Ni[CF3COCHC(C4H4S)=NCH2]2 WITH SOME FIVE-MEMBERED HETEROCYCLES BY GLC METHOD

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通讯作者: 陈斌, bchen63@163.com

STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDITIVE REACTION FOR Ni[CF₃COCHC(C₄H₄S)=NCH₂]₂ WITH SOME FIVE-MEMBERED HETEROCYCLES BY GLC METHOD