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Citation: Chen Yuanyin, Lu Xueran, Wang Zhongyu, Yang Yezhi. SYNTHESES OF POLYSILOXANE-SUPPORTED PHOSPHDINEPLATINUM, PHOSPHINE-RHODIUM COMPLEXES AND THEIR CATALYTIC BEHAVIOR FOR HYDROSILYLATION OF OLEFINES[J]. Chinese Journal of Applied Chemistry, ;1989, 6(3): 1-5. shu

SYNTHESES OF POLYSILOXANE-SUPPORTED PHOSPHDINEPLATINUM, PHOSPHINE-RHODIUM COMPLEXES AND THEIR CATALYTIC BEHAVIOR FOR HYDROSILYLATION OF OLEFINES

1.
1. Department of Chemistry, Wuhan University;
2.
2. Instrumental Analysis Center, Wuhan University

Received Date: 27 September 1988
Available Online: 3 December 1988

Poly-γ-(p-diphenyl phosphinophenyl)propyl siloxane platinum and rhodium complexes have been synthesized from γ-(p-chlorophenyl)-propyltrimethoxysilane via phosphatization with potassium diphenylphosphide,immobilization and hydrolysis on fumed silica,followed by reaction with potassium chloroplatinite or rhodium chloride. They exhibited high catalytic activity for the hydrosilylation of decene,dodecene, ω-chloroundecene, allyl benzene, phenyl allyl ethe, and allyl glycidyl ether with triethoxysilane from 80 to 100℃ and could be reused several times without loss of activity.
- Supported catalyst,
- Triphenylphosphine platinum complex,
- Triphenylphosphine rhodium complex,
- Hydrosilylation
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