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Citation: Lu Lude, Wang Xin, Song Qize, Yang Xujie. A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN^-[J]. Chinese Journal of Applied Chemistry, ;1989, 6(1): 63-65. shu

A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN^-

1.
Department of Chemical Engineering, East China Institute of Technology, Nanjing

Received Date: 23 January 1988
Available Online: 18 July 1988

This study deals with properties and thermal reactions of Co₃[Fe(CN)₆]₂ supported on silica, γ-alumina and magnesia. The final solid products of thermal decomposition in hydrogen atmosphere consisted of Co-Fe alloy and highly dispersed surface Fe(Ⅱ)ions.HCN was formed on silica and γ-alumina as a result of (CN)₂ hydrogenation. Neither HCN nor NH₃ was produced on magnesia because of the basicity of the support. Thus HCN may be considered as an intermediate of the hydrogenation process from(CN)₂ to NH₃.
- Cobalt ferricyanide,
- Cyanogen,
- Catalytic hydrogenation,
- Thermal reaetion
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A STUDY ON SUPPORTED CO₃[Fe(CN₆)]₂ AND HYDROGENATION OF CN^-