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Citation: Shi Xiaotian, Hao Tao, Wang Youliang, Wang Zonghua. OXIDATION OF(±)-2-(6-METHOXYL-2-NAPHTHYL) PROPIONIC ALDEHYDE TO CORRESPONDING ACID WITH H₂O₂ BY USE OF SeO₂ AS CATALYST[J]. Chinese Journal of Applied Chemistry, ;1986, 3(6): 61-63. shu

OXIDATION OF(±)-2-(6-METHOXYL-2-NAPHTHYL) PROPIONIC ALDEHYDE TO CORRESPONDING ACID WITH H₂O₂ BY USE OF SeO₂ AS CATALYST

1.
Chengdu Institute of Organic Chemistry, Academia Sinica

Received Date: 10 September 1985
Available Online: 29 May 1986

(±)-2-(6-Methoxyl-2-naphthyl)-propionic aldehyde has been oxidized to the corre-sponding acid with hydrogen peroxide by use of selenium dioxide as catalyst insteadof Tollen's reagent. The optimum conditions obtained are reported in this paper:catalyst/aldehyde=0. 01(wt), aldehyde/absolute ethyl alcohol=0.20(wt/vol), watercontent in the reaction medium 3%, H₂O₂/aldehyde=1-1.2(mol), reaction tempera-ture and time: 10-15℃ for 5 days. The yield of acid was 73.13%. less than that bysilver nitrate method. Content of Se in the product≤3ppm.
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OXIDATION OF(±)-2-(6-METHOXYL-2-NAPHTHYL) PROPIONIC ALDEHYDE TO CORRESPONDING ACID WITH H2O2 BY USE OF SeO2 AS CATALYST

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通讯作者: 陈斌, bchen63@163.com

OXIDATION OF(±)-2-(6-METHOXYL-2-NAPHTHYL) PROPIONIC ALDEHYDE TO CORRESPONDING ACID WITH H₂O₂ BY USE OF SeO₂ AS CATALYST